羧酸盐/磺酸盐复合型WPU胶黏剂的制备与表征

Preparation and characterization of carboxylate/sulfonate composite WPU emulsion adhesive

在以丙酮法合成固含量约为50%的磺酸盐WPU乳液胶黏剂的研究基础上,以羧酸盐改性磺酸盐WPU乳液胶黏剂制备复合型胶黏剂,研究了羧酸盐改性对磺酸盐型WPU胶黏剂性能的影响。结果表明,当DMPA用量1.6%,A95用量1.8%,聚酯多元醇中n(PBA2000)/n(PBA3000)为4/6,多异氰酸酯中n(HDI)/n(IPDI)为4/6时,WPU乳液黏度适中,分散稳定,耐水性良好,力学性能及粘接性能优异。红外光谱分析表明,成功合成了复合型WPU;DSC分析表明复合型WPU熔融温度约为48.03℃,磺酸盐WPU熔融温度为45.52℃,复合型WPU成峰面积更大,结晶性能更优;TEM分析显示,两种WPU乳液粒子均呈球形,均匀分散,粒径分布分析显示复合型WPU乳液粒径分布较磺酸盐WPU乳液更宽;GPC分析表明两种WPU分子量接近,改性对相对分子质量的影响不大;TGA分析表明550℃时到达热分解终点,磺酸盐WPU耐热性能稍占优势;综合性能分析结果显示两种胶黏剂都显示出良好的耐热性,力学性能及粘接性能方面,复合型WPU乳液胶黏剂明显有较大提高,同时其性能相比传统方法合成的羧酸/磺酸盐WPU也有较大提高。

Based on the study on preparation of sulfonate WPU emulsion adhesive of solid content at about 50% by the acetone method carboxylate-modified composite WPU emulsion adhesives was prepared. The impact of the modification on the properties of sulfonate WPU adhesive were also investigated. The results showed that when DMPA content was 1.6% （mass）, A95 content was 1.8% （mass）,n（PBA2000）/n（PBA3000） was 4/6 and n（HDI）/n（IPDI） was 4/6, the emulsion obtained a excellent mechanical and adhesive performance. Infrared spectroscopy showed that the composite WPU was prepared successfully. DSC analysis indicated that the melting temperature of composite WPU was about 48.03℃, while that of the sulfonate WPU was about 44.52℃. The composite WPU peak area were higher with better crystalline performance. TEM analysis revealed that both WPU emulsion particles were spherical and uniformly dispersed. Particle size distribution analysis showed that the particle size distribution of composite WPU emulsion was wider than that of the sulfonate WPU emulsion. GPC analysis displayed that the molecular weight of two types of WPU were similar, and thus the influence of modification on the molecular weight was small. TGA analysis found that the thermal decomposition reached the end at 550℃ with slight better heat resistance of sulfonate WPU. The integrated performance analysis showed that the two adhesives had better heat resistance, mechanical properties and adhesion performance, indicating that the performance of composite WPU emulsion adhesive was improved obviously, while its performance was also improved greatly as compared to the carboxylic/sulfonate WPU synthesised by the traditional method.