超交联微孔聚合物的制备及其应用的研究进展

Progress of the Preparation and Application of Hyper-cross-linked Polymers

超交联微孔聚合物(Hyper-cross-linked ploymers,HCPs)是一类新型多孔材料,由于其合成条件温和、成本低廉、孔尺寸可调控、表面官能团可修饰,以及耐热、耐酸碱等优点,近几年受到极大关注。在气体储存和分离、催化、去除水相中的重金属离子等方面具有明显的应用前景。本文介绍了超交联微孔聚合物的合成方法,包括通过外交联芳香化合物的方法和通过分子内或分子外交联前体的方法制备超交联微孔聚合物。总结了超交联微孔聚合物在储气,催化,废水处理等方面的应用。并对超交联微孔聚合物未来研究进行展望。

Hyper-cross-linked polymers （HCPs） are one of new type of porous materials, which get significant attention in recent years due to its mild synthetic conditions, low cost, adjustable pore size, modifiable functional groups, and heat resistant etc. HCPs have potential applications in gas storage and separation, catalysis, and the removal of heavy metal ions in aqueous phase. This article summarized the synthetic methods of HCPs, including via the external cross-linking of aromatic compounds and via the external cross-linking of intra-/extern- molecules Then the application of HCPs in gas storage, catalysis, waste water treatment etc was summarized. Finally, the perspective research of HCPs was discussed.