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开环易位聚合研究进展 被引量:6

Research Advances of Ring-opening Metathesis Polymerization
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摘要 简要介绍了开环易位聚合的基本情况,结合开环易位聚合相关研究报道,综述了开环易位聚合最新研究进展,着重介绍了新型聚合催化剂的研究与应用情况,特别是新型选择性催化剂、扩环复分解催化剂、负载型催化剂和结构不确定催化剂。在开环易位聚合研究与应用方面,重点介绍了遥爪型聚合物、嵌段聚合物、接枝共聚物和液晶聚合物的研究情况。在此基础上,指出了今后开环易位聚合的研究与应用方向。 The basic knowledge of ring-opening metathesis polymerization was briefly introduced. According to the recent reports,the recent research advances of ring-opening metathesis polymerization were reviewed. The recent research and application of new type polymerization catalysts,especially for new selected catalysts,ring-expanding metathesis catalysts,supported metal catalyst,and ill-defined catalysts,were focused on. The application of ring-opening metathesis polymerization in telechelic polymers,grafted polymers,block copolymers and liquid crystal polymers were also discussed. The development trends of ring-opening metathesis polymerization were proposed.
出处 《科学技术与工程》 北大核心 2015年第30期71-78,共8页 Science Technology and Engineering
关键词 开环易位聚合 催化剂 环烯烃 应用 综述 ring-opening metathesis polymerization catalyst cyclic olefin application review
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  • 1Truett W L, Johnson D R, Robinson I M, et al. Polynorbornene by coordination polymerization. J. Am. Chem. Soc., 1960, 82(9): 2337-2340.
  • 2Calderon N. Olefin metathesis reaction. Acc. Chem. Res., 1972, 5(4): 127-132.
  • 3He'risson J L, Chauvin Y. Catalyse de transformation des oléfines par les complexes du tungstène. II. Télomérisation des oléfines cycliques en présence d\'oléfines acycliques. Makromol. Chem., 1971, 141(1): 161-176.
  • 4Chauvin Y. Olefin metathesis: the early days (Nobel Lecture). Angew. Chem., Int. Ed., 2006, 45(23): 3740-3747.
  • 5Schrock R R. Multiple metal–carbon bonds for catalytic metathesis reactions (Nobel Lecture). Angew. Chem., Int. Ed., 2006, 45(23): 3748-3759.
  • 6Grubbs R H. Olefin-metathesis catalysts for the preparation of molecules and materials (Nobel Lecture). Angew. Chem., Int. Ed., 2006, 45(23): 3760-3765.
  • 7Calderon N, Chem H Y, Scott K W. Synthesis of 1-epihydantocidin from D-ribose. Tetrahedron Lett., 1967, 34 (20): 3327-3330.
  • 8Tebbe F N, Parshall G W, Reddy G S. Olefin homologation with titanium methylene compounds. J. Am. Chem. Soc., 1978, 100 (11): 3611-3613.
  • 9Wood C D, McLain S J, Schrock R R. Multiple metal-carbon bonds. 13. Preparation and characterization of monocyclopentadienyl mononeopentylidene complexes of niobium and tantalum including the first details of an .alpha.-abstraction process. J. Am. Chem. Soc., 1979, 101 (12): 3210-3222.
  • 10Wallace K C, Liu A H, Dewan J C, et al. Preparation and reactions of tantalum alkylidene complexes containing bulky phenoxide or thiolate ligands. Controlling ring-opening metathesis polymerization activity and mechanism through choice of anionic ligand. J. Am. Chem. Soc., 1988, 110 (15): 4964-4977.

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