摘要
从全氮化合物的结构与能量性能的关系进行理论探讨与预测,利用键能数据估算和比较了几种线性全氮化合物的能量,考察了几种可能大幅提高材料内能的线状、环状及笼状结构的全氮化合物。根据所得结果,建议全氮化合物的合成制备方向是在N+5的制备基础上进而合成立体笼状或者至少是环状全氮化合物。同时,提出几种可行性高并有应用前景的多氮化合物。
The performance related to structure of all-nitrogen energetic materials was reviewed.A method for calculating the energy of all-nitrogen materials with linear structure was proposed.It was suggested that the tridimensional cage structure or at least the cyclic annular structure could be in favor of ultra-high energy.At the same time,several kinds of poly-nitrogen materials with good prospect were introduced.
出处
《化工新型材料》
CAS
CSCD
北大核心
2015年第10期240-243,共4页
New Chemical Materials
关键词
全氮化合物
能量
结构
多氮化合物
all-nitrogen compound
energy
structure
poly-nitrogen compound
