期刊文献+

中和度对聚酯型阴离子WPU储存过程中耐水解性的影响

Influences of neutralization degree on hydrolysis resistance of polyester anionicwaterborne polyurethane during storage
下载PDF
导出
摘要 采用位阻因子为21的聚酯二元醇合成聚酯型阴离子WPU(水性聚氨酯),探讨了不同中和度对WPU的黏度、力学性能及储存稳定性的影响。研究结果表明:中和度越大,WPU的常温黏度越高、耐水解性越好且储存时间越长;当中和度为100%时,WPU的常温黏度、储存时间和力学性能相对最佳,可以满足工业领域的应用要求。 The polyester anionic WPU (waterborne polyurethane) was synthesized by polyester diol with sterie factor at 21, the influences of different neutralization degrees on WPU' s viscosity, mechanical property and storage stability were discussed. The research results showed that the neutralization degree was greater, so the WPU' s viscosity at room temperature was higher, the hydrolysis resistance was better, and the storage time was also longer.The WPU had the relatively optimal some properties (such as viscosity at room temperature, storage time and mechanical property), which could meet the application requirements in industrial field when neutralization degree was 100%.
作者 刘斌 曾俊
出处 《中国胶粘剂》 CAS 北大核心 2015年第10期40-43,共4页 China Adhesives
关键词 水性聚氨酯 中和度 聚酯二元醇 waterborne polyurethane (WPU) neutralization degree polyester diol
  • 相关文献

参考文献5

二级参考文献14

  • 1叶青萱.连续法合成聚氨酯水分散体[J].聚氨酯工业,2005,20(2):1-5. 被引量:5
  • 2Levchik S, Weil E D. Thermal decomposition, combustion and fire-retardancy of polyurethanes-a review of the recent literature[J]. Polym Int, 2004, 53: 1585-1610.
  • 3Rahman M M, Kim H D. Characterization of waterborne polyurethane adhesives containing different soft segments[J]. Journal of Adhesion Science Technology, 2007, 21 (12): 81-96.
  • 4Yen Mengshung, Tsai Hsiangchin, Hong Poda. Effect of soft segment composition on the physical properties of nonionic aqueous polyurethane containing side chain PEGME[J]. Journal of Applied Polymer Science, 2007, 105(3): 1391-1399.
  • 5Dieterich D.Prog Org Coat,9(1981)281.
  • 6Lorenz O,Budde V,Wirtz W,Angew.Makromol Chem,83(1979)113.
  • 7Hen J J.Colloid and Int Sci,1974,49,3.
  • 8Dieterich D. Aqueous emulsions, dispersions and solutions of polyurethane, synthesis and properties. Progress in Organic Coatings,1981, (9):281 -340.
  • 9Wolfgang H, Walter M, Peter F. Process for the Continuous Production of Aqueous Polyurethane Dispersions and Their Use as a Coating Composition or as an Adhesive. US P 4857565 (1989).
  • 10Schlaek P. Preparation of Aqueous Polymer Emulsion . DPB 920512(1943).

共引文献32

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部