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新型二维多酸化合物Na_3H_7[(BiW_9O_(33))_2Mn_4(H_2O)_(10)]·53H_2O的合成、晶体结构和性质研究

A New 2D Polyoxometalate Na_3H_7[( BiW_9O_(33))_2Mn_4(H_2O)_(10)]·53H_2O:Synthesis,Crystal Structure and Property
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摘要 以Na12[Bi2W22O74(OH)2]·44H2O、Ce Cl3·7H2O、Mn SO4·H2O和酒石酸钠Na2C4H4O6·2H2O为原料,采用常规水溶液合成方法制备了一例新颖的二维多酸化合物Na3H7[(Bi W9O33)2Mn4(H2O)10]·53H2O.通过单晶X射线衍射、红外光谱和热重对标题化合物进行了表征. A new 2D All-inorganic polyoxometalate compound Na3H7[（ Bi W9O33）2Mn4（ H2O）10]·53H2O was synthesized by the reaction of Na12[Bi2W22O74（ OH）2]·44H2O,Ce Cl3·7H2O,Mn SO4·H2O and Na2C4H4O6·2H2O in aqueous solution. The title compound was characterized by single-crystal X-ray diffraction,IR spectrum and thermogravimetric analysis.
作者 崔克宇 于国雷
机构地区 吉林师范大学环境友好材料制备与应用教育部重点实验室 吉林师范大学化学学院
出处 《吉林师范大学学报（自然科学版）》 2015年第4期109-112,共4页 Journal of Jilin Normal University:Natural Science Edition
基金 吉林师范大学博士科研启动项目(吉师博2013030)
关键词 多酸 合成 性质研究 polyoxometalate synthesis property
分类号 O61 [理学—无机化学]
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参考文献16

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吉林师范大学学报（自然科学版）
2015年 第4期

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