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新型含三氮唑苯并恶二唑衍生物的合成

Synthesis of new triazoly benzooxadiazole derivatives
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摘要 以二甲基吡啶胺、炔丙基溴和4-碘苯酚为原料,通过亲核取代反应、叠氮化反应、Click反应合成了中间体三氮唑化合物3,以2,6-二氯苯胺为原料经氧化反应、环化反应、硝化反应合成了中间体6,中间体3与6反应,合成了一种新型含三氮唑苯并恶二唑类化合物7,其结构经1H NMR和MS进行了表征。 An intermediate triazole compound 3 is synthesized via electrophilic substitution reaction, azidation reaction and Click reaction from bis（2-picolyl） amine, propargyl bromide and 4-iodophenol; intermediate 6 is synthesized from 2, 6-dichloroaniline by oxidation reaction, cyclization reaction and nitration reaction; a new triazoly benzooxadiazole compound is obtained by the reaction of intermediate 3 with intermediate 6; its structure is characterized by 1H NMR and MS.
作者 曹文艳 张春香 梁敏 邓艳 周路 申有名
机构地区 湖南文理学院化学化工学院
出处 《湖南文理学院学报（自然科学版）》 CAS 2015年第4期33-35,87,共4页 Journal of Hunan University of Arts and Science(Science and Technology)
基金 材料科学与工程湖南省大学生创新训练中心大学生研究性学习和创新性实验计划项目(15YCYB05) 湖南文理学院科学研究项目(14YB05) 湖南省十二五重点建设学科-应用化学资助
关键词 三氮唑 苯并恶二唑 合成 表征 triazole benzooxadiazole synthesis characterization
分类号 O626.2 [理学—有机化学]
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参考文献11

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湖南文理学院学报（自然科学版）
2015年 第4期

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