PCN高热稳定性介孔金属-有机骨架材料的合成

Manufacturation for Some Kinds of Highly Stable Mesoporous Metal-Organic Frameworks PCN

应用预先合成的[Fe3O(OOCCH3)6]作为基础原料合成了几种金属卟啉介孔金属-有机骨架材料,这类材料定义为PCN-600(M)(M=Cu,Fe,Co),具有介孔孔径尺寸,并且具有较大的孔容量.这几种材料中,PCN-600(Fe)在氧化反应中具有优秀的催化效果.

Several mesoporous metalloporphyrin MOFs ,namely PCN‐600（M） （M = Fe ,Co） ,have been synthesized using the preassembled[Fe3O（OOCCH3）6]building block .PCN exhibits a mesoporous pore size and the highest experimental pore volume among all the reported porphyrinic MOFs .PCN‐600（Fe） has been demonstrated as an effective peroxidase mimic to catalyze the co‐oxidation reaction in these materials .