联二萘酚衍生手性磷酸在亚胺不对称转移氢化反应中的应用研究进展

Research Progress on Asymmetric Transfer Hydrogenation of Imines Catalyzed by Chiral BINOL-Phosphoric Acid

综述了BINOL衍生手性磷酸在亚胺不对称转移氢化反应中的应用研究进展。根据亚胺不对称转移氢化反应中三类不同的氢供体——Hantzsch酯类氢源、2-取代苯并噻唑啉类氢源及其他氢源,对BINOL衍生手性磷酸催化的亚胺不对称转移氢化反应进行了重点介绍。参考文献53篇。

Research progress on asymmetric transfer hydrogenation of imines catalyzed by chiral BINOL-phosphoric acid were reviewed with 53 references. Based on the difference of three organic hydrogen donors——Hantzsch ester hydrogen source,2-substituted benzothiazole moiety hydrogen source and other hydrogen source,asymmetric transfer hydrogenation reactions of imines catalyzed by phosphoric acids were discussed in detail.