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Photocatalytic Performance of α- and β-Ga_2O_3 for the Degradation of Tetracycline Hydrochloride in Water

Photocatalytic Performance of α- and β-Ga_2O_3 for the Degradation of Tetracycline Hydrochloride in Water
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摘要 α- and β-Ga2O3 were prepared via a precipitation method. The as-prepared α- and β-Ga2O3 were characterized by X-ray diffraction (XRD), N2-sorption BET surface area, UV-vis diffuse reflectance spectra (DRS), photoluminescence spectroscopy (PL) and electron spin resonancespectroscopy (ESR). The photocatalytic activities of Ga2O3 were evaluated by the photocatalytic degradation of tetracycline sydrochloride solution. The results showed that the photocatalytic activity of β-Ga2O3 was higher than that of α-Ga2O3 and β-Ga2O3 obtained at the calcination temperature of 900℃, which showed the best photocatalytic activity. The reasons for the differences in photocatalytic activity of Ga2O3 are discussed in terms of crystallinity, surface area, crystals and electronic structures. α- and β-Ga2O3 were prepared via a precipitation method. The as-prepared α- and β-Ga2O3 were characterized by X-ray diffraction (XRD), N2-sorption BET surface area, UV-vis diffuse reflectance spectra (DRS), photoluminescence spectroscopy (PL) and electron spin resonancespectroscopy (ESR). The photocatalytic activities of Ga2O3 were evaluated by the photocatalytic degradation of tetracycline sydrochloride solution. The results showed that the photocatalytic activity of β-Ga2O3 was higher than that of α-Ga2O3 and β-Ga2O3 obtained at the calcination temperature of 900℃, which showed the best photocatalytic activity. The reasons for the differences in photocatalytic activity of Ga2O3 are discussed in terms of crystallinity, surface area, crystals and electronic structures.
出处 《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 2015年第11期1779-1785,共7页 结构化学(英文)
基金 supported by the Funds of Department of Education of Fujian province(No.JA14199)
关键词 GA2O3 tetracycline hydrochloride PHOTOCATALYSIS Ga2O3 tetracycline hydrochloride photocatalysis
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