Wien Effect in Suspensions of Electrodialyzed Soil Particles and Its Influencing Factors

The electrical conductivity of suspensions and their supernatants from theelectrodialyzed clay fractions of latosol, yellow-brown soil and black soil equilibrated withnitrate solutions were determined at different field strengths using a short high-voltage pulseapparatus to demonstrate the Wien effect in soil suspensions and to investigate factors affectingit. It was found that Wien effect was much stronger in suspensions with a clay content of 30 gkg^(-1) from the soils equilibrated with a 1 X 10^(-4) KNO_3 solution than in their supernatants.The threshold field strength (TFS), at which the relative conductivity is equal to 1.05, i.e., theWien effect begins to be obvious, of the yellow-brown soil suspensions (clay content of 30 gkg^(-1)) equilibrated with different nitrate solutions of a concentration of 1 X 10^(-4)/z molL^(-1), where z is the valence, varied with the type of nitrates, being lowest for NaNO_3 (47 kVcm^(-1)) and highest for Ca(NO_3)_2 (98 kV cm^(-1)). At high field strengths (larger than 130 kVcm^(-1)), the relative conductivities of yellow-brown soil suspensions containing different nitratesdiminished in the order: NaNO_3 > KNO_3 > Mg(NO_3)_2 > Zn(NO_3)_2 > Ca(NO_3)_2. The rates andintensities of the Wien effect in the suspensions of the three soils equilibrated with 5 X 10^(-5)mol L^(-1) Ca(NO_3)_2 solution were in the order of the yellow-brown soil > the latosol > the blacksoil. The results for the yellow-brown soil suspensions (clay concentration of 30 g kg )equilibrated with KNO_3 solutions of various concentrations clearly demonstrated that the moredilute the solution, the lower the TFS, and the larger the relative conductivity of the suspensionsat high field strengths. The results for yellow-brown soil suspensions with different clayconcentrations indicated that as the clay concentration increased, the low field electricalconductivity, EC_0, also increased, but the TFS decreased, and the Wien effect increased.

The electrical conductivity of suspensions and their supernatants from the electrodialyzed clay fractions of latosol, yellow-brown soil and black soil equilibrated with nitrate solutions were determined at different field strengths using a short high-voltage pulse apparatus to demonstrate the Wien effect in soil suspensions and to investigate factors affecting it. It was found that Wien effect was much stronger in suspensions with a clay content of 30 g kg-1 from the soils equilibrated with a 1 × 10-4 KNO3 solution than in their supernatants.The threshold field strength (TFS), at which the relative conductivity is equal to 1.05, i.e., the Wien effect begins to be obvious, of the yellow-brown soil suspensions (clay content of 30 g kg-1) equilibrated with different nitrate solutions of a concentration of 1 × 10-4/z mol L-1 , where z is the valence, varied with the type of nitrates, being lowest for NaNO3 (47 kV cm-1) and highest for Ca(NO3)2 (98 kV cm-1). At high field strengths (larger than 130 kV cm-1), the relative conductivities of yellow-brown soil suspensions containing different nitrates diminished in the order: NaNO3 ＞ KNO3 ＞ Mg(NO3)2 ＞ Zn(NO3)2 ＞ Ca(NO3)2. The rates and intensities of the Wien effect in the suspensions of the three soils equilibrated with 5 × 10-5 molL-1 Ca(NO3)2 solution were in the order of the yellow-brown soil ＞ the latosol ＞ the black soil. The results for the yellow-brown soil suspensions (clay concentration of 30 g kg-1) equilibrated with KNO3 solutions of various concentrations clearly demonstrated that the more dilute the solution, the lower the TFS, and the larger the relative conductivity of the suspensions at high field strengths. The results for yellow-brown soil suspensions with different clay concentrations indicated that as the clay concentration increased, the low field electrical conductivity, EC0, also increased, but the TFS decreased, and the Wien effect increased.