摘要
Herein, we present a novel way for the production of self-healing hydrogels with stretch beyond 4200% than their initial length and relatively high tensile strength （0.1-0.25 MPa）. Furthermore, the hydrogel was insensitive to notch. Even for the samples containing V-notches, a stretch of 2300% was demonstrated. The hydrogels were developed by in situ crosslinking of the self-assembled colloidal poly（acrylic acid） （PAA）/functionalized polyhedral oligomeric silsesquioxane （POSS） micelles. This was achieved by the addition of functionalized polyhedral oligomeric silsesquioxane with tertiary amines and hydroxyls （POSS-AH） into the PAA reaction solution. The POSS-AH led to micellar growth, then the dual- crosslinked network was constructed. One type of crosslink was formed by hydrogen-bonding and ionic interactions between PAA chains and POSS-AH, the other type of crosslink was formed by covalent bonds between PAA and bis（N,N＇-methylene- bis-acrylamide）.
Herein, we present a novel way for the production of self-healing hydrogels with stretch beyond 4200% than their initial length and relatively high tensile strength （0.1-0.25 MPa）. Furthermore, the hydrogel was insensitive to notch. Even for the samples containing V-notches, a stretch of 2300% was demonstrated. The hydrogels were developed by in situ crosslinking of the self-assembled colloidal poly（acrylic acid） （PAA）/functionalized polyhedral oligomeric silsesquioxane （POSS） micelles. This was achieved by the addition of functionalized polyhedral oligomeric silsesquioxane with tertiary amines and hydroxyls （POSS-AH） into the PAA reaction solution. The POSS-AH led to micellar growth, then the dual- crosslinked network was constructed. One type of crosslink was formed by hydrogen-bonding and ionic interactions between PAA chains and POSS-AH, the other type of crosslink was formed by covalent bonds between PAA and bis（N,N＇-methylene- bis-acrylamide）.
基金
financially supported by the Natural Science Foundation of Guangdong Province(No.2014A030313379)
the National Natural Science Foundation of China(Nos.81171459 and 31400824)
