5-甲胺基-4,6-二硝基苯并氧化呋咱及其中间体的合成

THE SYNTHESIS OF 5-METHYLAMINO-4, 6-DINITRO-BENZOFUROXAN AND ITS INTERMEDIATE COMPOUNDS

本文叙述了三个化合物5-甲胺基-2,4-二硝基叠氮苯(Ⅰ)、5-甲硝胺基-2,4,6-三硝基叠氮苯(Ⅱ)及5-甲胺基-4,6-二硝基苯并氧化呋咱(Ⅲ)的合成。通过对核磁共振氢谱的分析,确定了化合物(Ⅰ)与(Ⅲ)分别以一对几何异构体存在。本文中还对化合物(Ⅲ)的某些性质作了报告。

This paper describes the synthesis of three compounds: 5-methylamino-2, 4-dinitro azidobenzene (Ⅰ), 5-methyl nitro-amino-2, 4, 6-trinitro azidobenzene (Ⅱ) and title compound(Ⅲ). The 1~H NMR of (Ⅰ) and (Ⅲ) shows that a pair of steric isomerides exist respecvively. Some properties of(Ⅲ) are also reported.