摘要
用V_2O_5和草酸作为初始原料,在水热条件下合成了VO_2(A)纳米杆.通过改变初始的V_2O_5与草酸摩尔比以及反应时间制备纯相VO_2(A).样品的元素组成、微结构及光学性能分别被X射线光电子能谱(XPS)、X射线衍射(XRD)、扫描电镜(SEM)、差示扫描量热法(DSC)和傅里叶变换红外光谱(FT-IR)表征.实验结果表明合成VO_2(A)的最佳条件为:反应温度230℃、保温24h以及V_2O_5对草酸摩尔比为1∶1.5.结合XRD数据与SEM图像,提出一个转变、自组装和重结晶过程解释了VO_2(A)纳米棒的形成过程.
VO2(A)nanorods were facilely synthesized by using V2O5 and oxalic acid as the starting materials via a hydrothermal method.The initial molar ratio of V2O5 to oxalic acid and reaction time were changed to obtain the pure VO2(A)phase. The elemental composition,microstructures and optical properties of as-obtained VO2 samples were characterized using X-ray photoelectron spectroscopy(XPS),X-ray diffraction(XRD),scanning electron microscope(SEM),differential scanning calorimetry(DSC)and Fourier transform infrared spectrometer(FT-IR).It was found that the optimal synthesis condition of VO2(A)is hydrothermal process at 230 ℃ for 24 hwith a 1∶1.5molar ratio of V2O5/oxalic acid.Combining the XRD patterns and SEM images,a transformation,assembly,recrystallization process was proposed to explain the formation process of VO2(A)nanorods.
出处
《安徽大学学报(自然科学版)》
CAS
北大核心
2016年第1期42-49,共8页
Journal of Anhui University(Natural Science Edition)
基金
Supported by the National Science Foundation of China(11174001,51402002)
the Science Foundation of Anhui Education(KJ2013A030)
关键词
钒氧化物
VO2(A)
水热合成
相转变
红外光谱
vanadium oxides
VO2(A)
hydrothermal synthesis
phase transition
infrared spectroscopy