期刊文献+

以偏铝酸钠为催化剂实现由芳香甲腈到芳香甲酰胺的转化 被引量:1

An Efficient Hydration of Nitriles to Amides by Using a Sodium Aluminate Catalyst
下载PDF
导出
摘要 在水和乙醇混合溶剂中,以偏铝酸钠做催化剂,使芳香甲腈水解成芳香甲酰胺。偏铝酸钠的催化性能稳定,选择性高。该方法反应条件温和、成本低廉、产率较高、绿色环保,且具有较好的应用前景。 In aqueous and alcohol media,aromatic nitrile was hydrolyzed into aromatic amide by sodium aluminate as a potential catalyst. The catalytic reaction is stability and high selectivity. The method has advantages of mild reaction conditions,low cost and environment-friendly,and has a good application prospect.
出处 《化学试剂》 CAS 北大核心 2016年第1期7-10,79,共5页 Chemical Reagents
基金 陕西省教育厅产业化培育基金资助项目(2011JG03)
关键词 芳香甲腈 偏铝酸钠 催化 合成 芳香甲酰胺 aromatic nitriles sodium aluminate catalysis synthesis aromatic amides
  • 相关文献

参考文献28

  • 1龚跃法,郑炎松,陈东红,等.有机化学[M].武汉:华中科技大学出版社,2012.
  • 2GREENBERG A, BRENEMAN C M, LIEBMAN J F. Structural significance in chemistry, biochemistry, and materials science [ M ]. New York: John Wiley & Sons, 2000.
  • 3HUMPHREY J M ,CHAMBERLIN A R. Chemical synthe- sis of natural product peptides:coupling methods for the incorporation of noncoded amino acids into peptides [ J ]. Chem. Rev. ,1997,97(6) :2 243-2 266.
  • 4PORTER M C. Concentration polarization with membrane uhrafihration [ J ]. Ind. Eng. Chem. Res. , 1972,11 ( 3 ) : 234 -248.
  • 5MOORTHY J N ,SINGHAL N. Facile and highly selective conversion of nitriles to amides via indirect acid-catalyzed hydration using TFA or AcOH-H2SQ [ J ]. J. Org. Chem. ,2005,70(5):1 926-1 929.
  • 6KOVACS J A. Synthetic analogues of cysteinate-ligated non-heme iron and non-corrinoid cobalt enzymes [ J ]. Chem. Rev. ,2004,104 ( 2 ) : 825-848.
  • 7ENDO I, NOJIRI M,TSUJIMURA M, et al. Fe-type nitrile hydratase [ J ]. J. Inorg. Biochem. , 2001,83 ( 4 ) : 247- 253.
  • 8BLACK G W, GREGSON T, MCPAKE C B, et al. Bio- transformation of nitriles using the solvent-tolerant nitrile hydratase from Rhodopseudomonas palustris CGA009 [ J ]. Tetrahedron Lett. ,2010,51 (13) : 1 639-1 641.
  • 9PEPLOWSKI L,KUBIAK K,ZELEK S,et al. A compar- ative DFT study of substrates and products of industrial enzyme nitrile hydratase [ J ]. Int. J. Quantum Chem. , 2008,108 ( 1 ) : 161-179.
  • 10KIM E S,KIM H S, KIM J N. An efficient Pd-eatalyzed hydration of nitrile with acetaldoxime [ J ]. Tetrahedron Lett. ,2009,50(24) :2 973-2 975.

共引文献1

同被引文献1

引证文献1

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部