期刊文献+

化学溶剂离子液体研究进展 被引量:2

Research Progress on Application of Ionic Liquids
下载PDF
导出
摘要 离子液体作为一类性能优异、用途广泛、安全环保的新型环境友好的"绿色溶剂",具有熔点低、蒸气压小、电化学窗口大、酸性可调及良好的溶解度、粘度和密度等特点,在很多领域有着诱人的应用前景。离子液体易于循环利用,在化学反应中主要用于替代传统的有机溶剂从而减少对环境的污染,并使产率和选择性得以提高。随着研究的日益深入,已经被开发和应用到诸多领域。文中对离子液体在化学反应、分离提纯、电化学、催化合成以及化工方面的应用研究进展进行了综述,并对该领域的研究前景作了展望。 Ionic liquids, as a class of excellent performance, versatile, safe and environmental protective new environment-friendly green solvents, have characteristics of low melting point, low vapor pressure, wide electrochemical window, adjustable acidity, strong solubility, high viscosity and density and so on, they possess attractive prospect in many fields. Easily recycled utilize, ionic liquids are mainly used to substitute for traditional organic solvents in chemical reactions, thereby reducing environmental pollution and improve both yield and selectivity. With more in-depth study, ionic liquids have been exploited and applied to many other fields. Ionic liquids in chemical reaction, separation and purification, electrochemical, catalysis synthesis and chemical industry application were reviewed, and research prospects were described.
作者 曾理
出处 《广州化工》 CAS 2016年第1期44-45,58,共3页 GuangZhou Chemical Industry
关键词 离子液体 绿色溶剂 应用 ionic liquids green solvent application
  • 相关文献

参考文献13

  • 1吴清文.离子液体及其研究进展[J].中国科技信息,2008(9):45-46. 被引量:6
  • 2何鸣元,戴立益.离子液体与绿色化学[J].化学教学,2002(6):1-3. 被引量:20
  • 3李汝雄,王建基.离子液体的合成与应用[J].化学试剂,2001,23(4):211-215. 被引量:89
  • 4Berson J. A. , Hamlet Z. , Mueller W. A. The Correlation of Solvent Effects on the Stereoselectivities of Diels-Alder Reactions by Means of Linear Free Energy Relationships. A New Empirical Measure of Solvent Polarity [ J]. Journal of the American Chemical Society, 1962,84 ( 2 ) : 297-304.
  • 5Fischer T. , Sethi A. , Wehon T. , Woolf J. Diels-Alder reactions in room- temperature ionic liquids [ J ]. Tetrohedron Letters, 1999,40 (4) : 793 - 796.
  • 6Ranu B. C. , Banerjee S. Ionic Liquid as Catalyst and Reaction Medium. The dramatic influence of a task-specific ionic liquid, [ bmim] OH, in Michael addition of active methylene compounds to conjugated ketons, carboxylic ester, and nitriles [ J ]. Organic Letters, 2005,7 ( 14 ) : 3049- 3052.
  • 7李文波,辛炳炜.离子液体中Heck反应的研究进展[J].德州学院学报,2008,24(6):65-68. 被引量:1
  • 8Kumaravel Selvakumar, Alexander Zapf, Matthias Belier. New Palladium Carbene Catalysts for the Heck Reaction of Aryl Chlorides in Ionic Liquids [J]. Organic Letters, 2002,(4):3031-3033.
  • 9Sandrine Bouquillon, Benjamin Ganchegui, Boris Estrine, Franoise H6nin, Jacques Muzart. Heck arylation of allylic alcohols in molten sahs [ J]. Joumal of Organometallic Chemistry,2001,634(2) : 153-156.
  • 10XIE Hai-bo, ZHANG Suo-bo,Duan Hai-feng. An ionic liquid based on a cyclic guanidinium cation is an efficient medium for the selective oxidation of benzyl alcohols [ J ]. Tetrahedron Letters, 2004,45 ( 9 ) : 2013-2015.

二级参考文献49

  • 1叶君,赵星飞,熊犍.离子液体在纤维素研究中的应用[J].化学进展,2007,19(4):478-484. 被引量:24
  • 2石峰 邓友全 等.-[J].化学通报(网络版),2000,4:0003-0003.
  • 3北爪智哉.-[J].化学工业(日),2000,(6):29-29.
  • 4北爪智哉.-[J].机能材料(日),2000,20(1):54-54.
  • 5Poliakoff M, Fitzpatrick J M, Farren T R, et al. Green chemistry: science and politics of change[J]. Science, 2002, 297: 807-810.
  • 6Desimone J M. Practical approaches to green solvents[J]. Science, 2002, 297: 799-803.
  • 7Welton T. Room--temperature ionic liquids. Solvents for synthesis and catalysis[J]. Chem. Rev. 1999, 99: 2071--2083
  • 8Dupont J, de Souza R F, SuarezP A Z. Ionic liquid (molten salt) phase organometallic catalysis[J]. Chem. Rev. 2002, 102: 3667-3692
  • 9Tzschueke C C, Markert C, Bannwarth W, et al. Modern separation techniques for the efficient workup in organic synthesis[J]. Angew. Chem. , Int. Ed. 2002, 41:3964 --4000.
  • 10Adrian J. Carmichael, Martyn J. Earle, John D. Holbrey, et al. The Heck Reaction in Ionic Liquids.. A Multiphasic Catalyst System [J]. Org. Lett. , 1999,(1):997--1000.

共引文献124

同被引文献38

引证文献2

二级引证文献13

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部