期刊文献+

Visible-light-promoted and photocatalyst-free trifluoromethylation of enamides

Visible-light-promoted and photocatalyst-free trifluoromethylation of enamides
原文传递
导出
摘要 An efficient and practical method is developed for the trifluoromethylation of enamides using Umemoto's reagent as the trifluoromethylating reagent. These reactions proceeded under visible light irradiation without any photocatalyst at room temperature in good chemical yields. An efficient and practical method is developed for the trifluoromethylation of enamides using Umemoto's reagent as the trifluoromethylating reagent. These reactions proceeded under visible light irradiation without any photocatalyst at room temperature in good chemical yields.
出处 《Science China Chemistry》 SCIE EI CAS CSCD 2016年第2期195-198,共4页 中国科学(化学英文版)
基金 supported by the National Natural Science Foundation of China(21472084 81421091) the Qing Lan Project of Jiangsu Province and State Key Laboratory of Bioorganic & Natural Products Chemistry Shanghai Institute of Organic Chemistry Chinese Academy of Sciences
关键词 ENAMIDE PHOTOCHEMISTRY visible light TRIFLUOROMETHYLATION radical 可见光照射 三氟甲基 光触媒 甲基化试剂 免费 开发利用 化学产率 光催化剂
  • 相关文献

参考文献33

  • 1Erickson KL, Beutler JA, Cardellina Ⅱ JH, Boyd MR.J Org Chem, 1997, 62:8188-8192.
  • 2Kohno J, Koguchi Y, Nishio M, Nakao K, Kuroda M, Shimizu R, Ohnuki T, Komatsubara S.J Org Chem, 2000, 65:990-995.
  • 3Yet L.Chem Rev, 2003, 103:4283-4306.
  • 4For representative reviews on enamines:a) Gopalaiah K, Kagan HB.Chem Rev, 2011, 111:4599-4657.
  • 5Carbery DR.Org Biomol Chem, 2008, 6:3455-3460.
  • 6Matsubara R, Kobayashi S.Acc Chem Res, 2008, 41:292-301.
  • 7Kagan HB, Dang TP.J Am Chem Soc, 1972, 94:6429-6433.
  • 8Wang Q, Huang W, Yuan H, Cai Q, Chen L, Lv H, Zhang X.J Am Chem Soc, 2014, 136:16120-16123.
  • 9Xie JH, Zhu SF, Zhou QL.Chem Soc Rev, 2012, 41:4126-4139.
  • 10Berthiol F, Matsubara R, Kawai N, Kobayashi S.Angew Chem Int Ed, 2007, 46:7803-7805.

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部