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两个含2-(1H-苯并咪唑基)-4-溴苯酚的钴(Π)、锌(Π)配合物的合成、晶体结构及表征 被引量：2

Synthesis,Crystal Structure and Properties of Co(Ⅱ),Zn(Ⅱ)Complexes with 2-(1H-benzimidazol-2-yl)-4-bromophenolato
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摘要 以乙酸钴、2-(1H-苯并咪唑基)-4-溴苯酚为原料通过水热法自组装成新型的配合物[Co(C_(13)H_8BrN_2O)_2]·2(CH_3OH)1;乙酸锌和2-(1H-苯并咪唑基)-4-溴苯酚通过自然挥发法自组装成新型的配合物[Zn(C_(13)H_8BrN_2O)_2]·DMF·3H_2O_2.X射线单晶衍射结果表明配合物1和2都属于三斜晶系,Pī空间群,具有相似的晶胞参数,属于同构体.配合物1通过氢键的作用形成一维链状结构,配合物2通过氢键的作用形成二维层状结构.两者的荧光及热稳定表征结果表明,配合物2比配合物1的荧光强度高. The complex 1[Co（C13H8BrN2O）2]·2 （CH3OH） were self-assembled with Co（CH3COO）2·4H2 O and the 2-（1H-benzimidazol-2-yl）-4-bromophenolato as raw material by a hydrothermal method and the same ligands with Zn（CH3 COO）2·2H2O by natural evaporation method self-assemble into complex 2[Zn（C13 H8BrN2O）2]· DMF·3H2O. And the crystal structure of the complexes was characterized by X-ray crystal diffraction. The results show that the complexes 1 and 2 crystallize in triclinic, space group P1. Complex 1 assembles into a 1D chain structure by the intermolecular hydrogen bonding interactions and the complex 2 assembles into a 2D layer structure. The fluorescent property and thermal stability are also studied, the results show that complex 2 with stronger fluorescence intensity than complex 1.
作者 范艳 瞿志荣
机构地区 杭州师范大学有机硅化学及材料技术教育部重点实验室
出处 《杭州师范大学学报（自然科学版）》 CAS 2016年第1期1-6,共6页 Journal of Hangzhou Normal University(Natural Science Edition)
关键词 2-(1H-苯并咪唑基)-4-溴苯酚 配合物 晶体结构 荧光 2-（1H-benzimidazol-2-yl）-4 bromophenolato complex crystal structure fluorescent
分类号 O614.241 [理学—无机化学] O614.241 [理学—无机化学]
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参考文献13

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共引文献6

同被引文献6

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杭州师范大学学报（自然科学版）
2016年 第1期

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