摘要
Two novel coordination compounds,1[Zn4（L1）4（NO3）2（H2O）2]（NO3）2·2H2O and 2[Mn2（L2）2（DMF）（H2O）3]（ClO4）2·DMF（HL1 = N＇-[（1E）-pyridine-2-ylmethylidene]pyrazine-2-carbohydrazide,H2L2 = 2-hydroxy-3-methoxybenzaldehyde（pyrazin-2-ylcarbonyl）hydrazone）,based on the N-N bridged ligands were prepared and structurally characterized.Compound 1represents the[2＊2]molecular squares,in which both N atoms belonging to the N-N bridged ligands are connected to the Zn centers.The emission of compound 1 exhibits a blue shift,which can be assigned to strong electrostatic interaction between Zn^Ⅱ ions and the L1^-1.Compound 2represents a rare phenol-O bridged Mn2^Ⅱ complex.The magnetic investigation indicates weak antiferromagnetic interactions between the Mn^Ⅱ centers.
Two novel coordination compounds,1[Zn4（L1）4（NO3）2（H2O）2]（NO3）2·2H2O and 2[Mn2（L2）2（DMF）（H2O）3]（ClO4）2·DMF（HL1 = N＇-[（1E）-pyridine-2-ylmethylidene]pyrazine-2-carbohydrazide,H2L2 = 2-hydroxy-3-methoxybenzaldehyde（pyrazin-2-ylcarbonyl）hydrazone）,based on the N-N bridged ligands were prepared and structurally characterized.Compound 1represents the[2＊2]molecular squares,in which both N atoms belonging to the N-N bridged ligands are connected to the Zn centers.The emission of compound 1 exhibits a blue shift,which can be assigned to strong electrostatic interaction between Zn^Ⅱ ions and the L1^-1.Compound 2represents a rare phenol-O bridged Mn2^Ⅱ complex.The magnetic investigation indicates weak antiferromagnetic interactions between the Mn^Ⅱ centers.
基金
supported by the National Basic Research Program of China(973 Program
2012CB821702)
the National Natural Science Foundation of China(21233009 and 21173221)
the State Key Laboratory of Structural Chemistry,Fujian Institute of Research on the Structure of Matter,Chinese Academy of Sciences
