摘要
A quench-treatment technique is used to prepare a high-quality polycrystalline sample of double perovskite Sr2FeMo06 （SFMO）. X-ray powder diffraction analysis reveals that the sample has a single phase and exhibits I4/m symmetry. The cation order η of the sample increases to 98.9（2）% from 94.2（3）%, which is prepared by the traditional sol-gel method. The initial magnetization isotherm of the sample is detected at 300 K. Unit-cell magnetization for the current sample is 1.332 #s at 300 K, and the one for the traditional sol-gel method sample is 0.946#9. Unit-cell magnetization is enhanced to 40.80% by the quench-treatment technique. Quench treatment is an effective method of enhancing the Fe/Mo order and magnetic properties of double perovskite SFMO.
A quench-treatment technique is used to prepare a high-quality polycrystalline sample of double perovskite Sr2FeMo06 （SFMO）. X-ray powder diffraction analysis reveals that the sample has a single phase and exhibits I4/m symmetry. The cation order η of the sample increases to 98.9（2）% from 94.2（3）%, which is prepared by the traditional sol-gel method. The initial magnetization isotherm of the sample is detected at 300 K. Unit-cell magnetization for the current sample is 1.332 #s at 300 K, and the one for the traditional sol-gel method sample is 0.946#9. Unit-cell magnetization is enhanced to 40.80% by the quench-treatment technique. Quench treatment is an effective method of enhancing the Fe/Mo order and magnetic properties of double perovskite SFMO.
基金
Supported by the National Natural Science Foundation of China under Grant No U1304110
the Doctoral Science Foundation of Henan Normal University under Grant No 01026500109
