摘要
本文首次提出一种计算冠醚空穴半径的通用方法(2π法),并对152种冠醚(单给体冠醚24种,多给体冠醚128种,给体原子总数均不超过10)进行了计算,计算值精确到0.01(?)。除了为数不多的几种单给体含氧冠醚外,均为首次得到的值。
A general method is proposed for calculating cavity radii of crown compounds. A practical calculation is thus performed and the cavity radii of 152 crown compounds are obtained. Twenty four of them are simple donor type. Others are composite donor type, each containing more than one kind of donor atoms.
出处
《北京师范大学学报（自然科学版）》
CAS
1986年第3期54-60,共7页
Journal of Beijing Normal University(Natural Science)
