摘要
In this study,a hydrophobic synthetic zeolite,namely ZSM-5 is chosen as an adsorbent/catalyst for toluene removal.Experimental results showed that toluene adsorption onto ZSM-5 was favourable,following a Langmuir adsorption isotherm model.ZSM-5 zeolite was regenerated using gaseous ozone at low temperature.Adsorbed toluene was oxidised,releasing mainly CO_2 and H_2O.Traces of oxidation by-products such as acetic acid and acetaldehyde were formed and remained adsorbed after the oxidativate regeneration with ozone.After four successive cycles of adsorption/ozonation,the adsorption efficiency was not affected（92%-99%）.These results showed that volatile organic compound（VOC）removal by adsorption onto ZSM-5 zeolite followed by ozone regeneration could be used as a promising hybrid process for the control of VOC emissions in terms of efficiency.
In this study,a hydrophobic synthetic zeolite,namely ZSM-5 is chosen as an adsorbent/catalyst for toluene removal.Experimental results showed that toluene adsorption onto ZSM-5 was favourable,following a Langmuir adsorption isotherm model.ZSM-5 zeolite was regenerated using gaseous ozone at low temperature.Adsorbed toluene was oxidised,releasing mainly CO_2 and H_2O.Traces of oxidation by-products such as acetic acid and acetaldehyde were formed and remained adsorbed after the oxidativate regeneration with ozone.After four successive cycles of adsorption/ozonation,the adsorption efficiency was not affected（92%-99%）.These results showed that volatile organic compound（VOC）removal by adsorption onto ZSM-5 zeolite followed by ozone regeneration could be used as a promising hybrid process for the control of VOC emissions in terms of efficiency.
基金
the Centre National pour la Recherche Scientifique et Technique of Morocco(CNRST)
the Centre National de la Recherche Scientifique of France(CNRS)with the Project(CNRST/CNRS Grant No.SPI 05/13)
Comisión Nacional de Investigación Científica y Tecnológica(CONICYT)of Chile and Fondo Nacional de Desarrollo Científico y Tecnológico of Chile(FONDECYT)with the Project(CONICYT/FONDECYT Grant No.1130560)
Comitéde Evaluation-orientation de la Coopération Scientifique of France(ECOS)and Comisión Nacional de Investigación Científica y Tecnológica of Chile(CONICYT),with the project(ECOS/CONICYT Grant No.C11E08)
