摘要
SUS301不锈钢端子的高速电镀层,受镀件表面的平整度,高速冲压拉伸后的相变、形貌,槽液体系,工艺流程等影响极大。另外,由于氨基磺酸盐镀镍液体系所得镀镍层上形成胶体膜[Ni(OH)_2],随后镀金层中产生大量气泡、针孔,导致镀层硬、脆、结合力差等不良。采用无铬电解抛光与阳极电解活化前处理工艺,改善镀件表面的不良状态,并在刷镀金前对镀镍层作10%(体积分数)硫酸溶液浸渍,以中和镀镍层上的胶体膜。处理后的电镀层可通过硝酸、高温高湿、中性盐雾等例行考核。
The high-speed electroplated coating on SUS301 stainless steel connector is greatly affected by material surface flatness, phase transformation and morphology caused by stretching after high-speed stamping, plating bath composition, process flow and other factors. The colloidal Ni(OH)2 film formed on nickel coating obtained from a sulfamate bath causes hard, brittle and poor-adhered gold coating plated subsequently due to the formation of bubbles and pinholes in the gold coating. The chromium-free electropolishing and anodic electro-activation processes were employed to improve the state of material surface. The colloidal film on nickel coating is neutralized by immersing it into a 10vol% sulfuric acid solution prior to gold brush-plating. The improvements make the coatings possible to go through all severe tests, such as nitric acid test, damp heat test and neutral salt spray test.
出处
《电镀与涂饰》
CAS
CSCD
北大核心
2016年第5期242-249,共8页
Electroplating & Finishing
关键词
不锈钢端子
高速电镀
镍
金
电解抛光
阳极电解活化
中和
耐蚀性
stainless steel connector
high-speed electroplating
nickel
gold
electropolishing
anodic electro-activation
neutralization
corrosion resistance