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纳米磷酸钡在环氧涂层中的防腐蚀机理研究 被引量:3

Anticorrosion Mechanism of Epoxy Coating with Nano-flake Barium Phosphate
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摘要 通过水热法制备片状纳米磷酸钡,利用电化学阻抗谱和盐雾试验测试方法,研究纳米磷酸钡对环氧涂层耐蚀性的影响。研究发现,环氧涂层中纳米磷酸钡与金属基体腐蚀产物Fe O反应生成不溶性Fe PO4,在腐蚀区形成隔离层,进而提高涂层的耐蚀性,在本实验中添加5%片状纳米磷酸钡环氧涂层的耐蚀性最高。 Nano- flake barium phosphate was prepared by hydrothermal synthesis, and then the effect of which as pigment on the corrosion behavior of epoxy coating was investigated by means of electrochemical impedance spectroscopy(EIS) and salt spray tests. The results show that the nano-flake barium phosphate in the epoxy coating can react with iron oxide, the corrosion product of metal substraste,to generate an insoluble Fe PO4 as a barrier on the corrosion spot, thereby to enhance the corrosion resistance of the coating; Among others, an epoxy coating with 5 mass% nano flake barium phosphate shows the highest corrosion resistance.
出处 《材料研究学报》 EI CAS CSCD 北大核心 2016年第3期192-198,共7页 Chinese Journal of Materials Research
基金 广东省中国电器院风电装备腐蚀控制关键技术院士工作站项目2013B090400023 国家电网公司科技项目zdk/gw001-2012资助~~
关键词 复合材料 纳米磷酸盐 输电线路杆塔 电力设施防护 composite nanometer phosphate transmission line tower protection for electric power facilities
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  • 1曹楚南.腐蚀电化学中的频谱分析研究[J].腐蚀科学与防护技术,1993,5(1):1-9. 被引量:11
  • 2骆明.新一代磷酸锌系防锈颜料——磷酸铝锌的合成和应用[J].化工技术与开发,2004,33(6):8-10. 被引量:7
  • 3梁峰,张鉴清,刘宏伟,许淑琴,曹楚南,林海潮,董建梁,蔡兆英.涂层/基体界面污染程度对有机涂层防护性能的影响[J].中国腐蚀与防护学报,1993,13(1):70-75. 被引量:6
  • 4袁爱群,白丽娟,宋宝玲,龚福忠.ZnO-P_2O_5-H_2O反应体系磷酸锌颜料的防锈活性研究[J].涂料工业,2005,35(9):16-18. 被引量:5
  • 5PEDRO DE LIMA - NETO, ADRIANA N CORREIA. Study of the anticorrosive behaviour of epoxy binders containing non - toxic inorganic corrosion inhibitor pigments[J]. Progress in Organic Coatings, 2008, 62 : 387 - 394.
  • 6BETHENCOURT M, BOTANA F J, MARCOS M, et al. Inhibitor properties of" green" pigments for paints [ J ]. Progress in Organic Coatings, 2003, 46: 280- 287.
  • 7PETR KALENDA,ANDREA KALENDOVA,PERT MOSNER,et al.Efficiency of anticorrosive pigments based on modified phosphates [J]. Macromol Symp, 2002, 187 : 397 -406.
  • 8MAI,GORZATA ZUBIELEWICZ, WITOLD GNOT. Mechanisms of non - toxic anticorrosive pigments in organie waterborne coatings [J]. Progress in Organic Coatings, 2004, 49:358 -371.
  • 9MALGORZATA ZUBIELEWICZ, ELZBIETA KAMINSKA, JACEK BORDZILOWSK1. Forecasting and optimisation of the waterborne anticorrosive paint composition with nontoxic pigment[ J]. Macrotool Syrup, 2002, 187: 147- 154.
  • 10DA JONES. Principles and prevention of corrosion [ M ]. New York: Macmillan : 1992.

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