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负载Zr(Ⅳ)的水解废弃皮革对氟离子的吸附性能 被引量:10

Adsorption of fluorion onto hydrolyzed leather waste impregnated with zirconium(Ⅳ)
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摘要 将锆(Ⅳ)负载在通过氢氧化钠(Na OH)水解的粒状废弃皮革上制备出新型氟离子(F-)吸附剂。采用扫描电子显微镜(SEM)、X射线能量色散光谱分析(EDX)、X射线光电子能谱分析(XPS)、傅里叶变换红外吸收光谱分析(FTIR)等方法研究了该吸附剂对水溶液中F-的吸附特性及其吸附机理。结果表明:研究条件下,粒状废弃皮革与Zr(NO_3)_4·5H_2O最优的质量比为1:3;该吸附剂对F-的最优吸附p H为4;该吸附剂对F-的吸附等温线符合Langmuir方程,拟合得出对F-的饱和吸附量为30.56 mg·g^(-1);吸附动力学可用准二级动力学模型描述,属化学吸附,F-以离子交换的形式代替羟基(—OH)与吸附剂中的Zr(Ⅳ)结合形成稳定的化学键,从而达到吸附水溶液中氟离子的目的。 A novel adsorbent was prepared from hydrolyzed granular leather waste(ZHGLW) impregnated with Zr(Ⅳ) for fluorion removal. Fluorion adsorption performance and mechanism were investigated by scan electron microscope, energy dispersive analysis of X-ray, X-ray photoelectron spectroscope, and Fourier transform infrared spectroscopy. The results indicate that the optimal mass ratio of hydrolyzed granular leather waste and Zr(NO3)4·5H2O is 1:3 in this study. The maximum removal of fluorion is obtained at p H 3. The isotherm data fit the Langmuir isotherm model well and the obtained maximum fluorion adsorption capacity of the sorbent is 30.56 mg·g^-1. The kinetics of fluorion adsorption onto ZHGLW follows the pseudo-second-order model. Fluorion adsorption process is a chemisorption process, which can be described as that —OH is replaced by fluorion in the form of ion exchange and a stable chemical bond forms through fluorion and impregnated Zr(Ⅳ). Thus, ZHGLW could be an efficient adsorbent for fluorion.
出处 《化工学报》 EI CAS CSCD 北大核心 2016年第4期1368-1377,共10页 CIESC Journal
基金 国家核能开发专项课题(13zg610301) 国家自然科学基金项目(21406182)~~
关键词 废弃皮革 负载 氟离子 吸附 离子交换 吸附剂 granular leather waste impregnated fluorion adsorption ion exchange adsorbent
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