氯化亚锡和纳米二氧化硅对PET材料表面亲水性影响

Effects of SnCl_2 and Nano-silica on Hydrophilicity of PET Materials

目的提高PET材料的表面亲水性。方法氯化亚锡与PET共混成膜后,采用共混接枝法,在共混膜表面接枝氨基化改性的纳米二氧化硅,制备出强亲水的PET材料。采用静态接触角、傅里叶变换红外光谱仪、原子力显微镜测试手段对PET材料表面进行表征。结果氨基化改性的纳米二氧化硅能够成功接枝在氯化亚锡与PET共混材料表面。当氯化亚锡质量分数为0.3%时,共混膜接触角由98°下降到74.5°。共混膜接枝氨基化改性的纳米二氧化硅溶液20 h时,PET材料表面接触角由74.5°下降到7.8°,亲水性得到了极大提高。接枝膜浸泡于蒸馏水10 d后,PET材料表面接触角由7.8°上升至34.9°。结论氯化亚锡与PET材料共混,接枝氨基化改性的纳米二氧化硅后极大地提高了PET材料表面的亲水性。

Objective To improve the surface hydrophilicity of PET materials. Methods In this paper,highly hydrophilic PET materials were prepared by blending with SnCl2 and then grafting amination-modified nano-silica on the surface of the blended film.The surface properties of PET materials were characterized by static contact angle measurement,Fourier transformed infrared spectroscopy and atomic force microscopy. Results The results showed that amination-modified nano-silica was successfully grafted on the surface of the SnCl2/ PET blended materials. When the content of SnCl2 was 0. 3% in PET materials,the surface contact angle of blending membrane dropped from 98° to 74. 5°. The surface contact angle of PET materials dropped from 74. 5° to 7. 8° after the blending membrane was grafted with amination-modified nano-silica for 20 h,and the hydrophilicity was increased dramatically.The surface contact angle of PET materials increased from 7. 8° to 34. 9°after the grafted membrane was soaked in distilled water for10 d. Conclusion The surface hydrophilicity of PET materials was improved greatly by blending with SnCl2 and then grafting amination-modified nano-silica.