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超分子体系移位[2+2]环加成制备高分子的研究进展

Development of Dystopy [2+2]Cycloaddition Reactions in Supramolecular Systems for the Preparation of Polymers
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摘要 综述了光催化下移位[2+2]环加成制备高分子的研究进展,总结了在有机超分子和金属-有机配位超分子结晶体系中完成光聚合的条件,内容包括分子结构、晶格数据、实验及表征等。该方法借助现代技术手段,具有先进、绿色、高效等优点,是制备具有精确微观结构的新颖高分子的首选策略。 Development of dystopy [2 ＋ 2]cycloaddition reactions for the preparation of polymers was reviewed,and the conditions of photopolymerization in organic and metal-organic supramolecular crystal systems were summarized,including molecule structures,data of crystal lattice,experiments,characterization,etc.For the preparation of novel polymers with precise microstructures,this was an advanced,efficient and environmentally friendly preferred strategy supported from modern technology.
作者 杨鑫 虞哲 于方舟 傅雪莲 黄坤林
机构地区 重庆师范大学化学学院
出处 《广州化工》 CAS 2016年第7期17-20,共4页 GuangZhou Chemical Industry
基金 高级化学品绿色合成与应用重庆高校创新团队(KJTD201309)
关键词 超分子结晶体系 光聚 移位[2+2]环加成 高分子 金属-有机框架 supramolecular crystal system photopolymerization dystopy [2＋2]cycloaddition polymer metalorganic framework
分类号 O622.1 [理学—有机化学]
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参考文献16

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二级参考文献7

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广州化工
2016年 第7期

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