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一种高选择性氰离子荧光探针的研究 被引量：4

A highly selective new fluorescent probe for detection of cyanide
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摘要 本文通过9-蒽甲醛与2-氨基-4-硝基苯酚反应合成了分子探针L,用1H-NMR对其结构进行了表征。在乙醇-水的混合溶液中运用荧光光谱对其进行聚集荧光性能的测试,实验结果表明这种分子具有聚集荧光增强的性质。并在乙醇和水混合液的体系下,对阴离子进行识别测试,结果表明探针L对氰离子的最低检测限为1.021×10^(-4)mol·L^(-1),对氰离子实现了高效识别。 A chemistry probe L was synthesized through 9-Anthraldehyde and 2-Amino-4-nitrophenol.Its structure was characterized by using1H-NMR.The Aggregation induced enhanced emission（AIEE） characteristics was studies in mixed solvent ethanol with water,the result showed that the probe had AIEE character. The minimum detection limit of L for CN^- was 1. 021＊ 10^（-4）M,and this probe molecular expressed high selective to CN-in mixed solvent ethanol with water.
作者 边延江 曹福祥 王璐琼 汤立军
机构地区 渤海大学化学化工学院
出处 《化学研究与应用》 CAS CSCD 北大核心 2016年第4期492-496,共5页 Chemical Research and Application
基金 国家自然科学基金项目(21176029)资助 国家自然科学基金项目(21476029)资助
关键词 9-蒽甲醛 2-氨基-4-硝基苯酚 席夫碱 聚集荧光增强 氰离子识别 9-Anthraldehyde 2-Amino-4-nitrophenol Schiff base aggregation-induced emission enhance-ment anion CN-recogni tion
分类号 O657.3 [理学—分析化学]
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参考文献18

  • 1Luo J D,Xie Z L,Lam J W Y,et al. Aggregation-induced emission of 1-methy|-I, 2,3,4,5-pentaphenylsilole [J]. Chem Commun ,2001 , 18 : 1740-1741.
  • 2Hong Y, Lain J W Y, Tang B Z. Aggregation-induced emis- sion:Phenomenon,mechanism and applications [J]. Chem Commun,2009 ,29 :4332 -4353.
  • 3Huang C Y,Wan C F, Chir J L, et al. A Schiff-based col-orimetric fluorescent sensor with the potential for detection of fluoride Ions [J]. J Fluoresc, 2013,23 : 1107-1111.
  • 4Udhayakumari D, Saravanamoorthy S, Ashok M. Simple imine linked eolorimetric and fluorescent receptor for sens- ing Zn2. ions in aqueous medium based on inhibition of ESIPT mechanism [J]. Tetrahedron Lett, 2011,52 : 4631- 4635.
  • 5Fang B Y, Liang Y, Chen F. Highly sensitive and selective determination of cupric ions by using N, N' -bis ( salicyli- dene)-o-phenylenediamine as fluorescent chemosensor and related applications [J]. Talanta,2014 ,119 :601-605.
  • 6Tomasulo M, Sortino S, White A J P, et al. Chromogenic oxazines for cyanide detection. [J]. Org Chem,2006,71 : 744-53.
  • 7Anzenbacher P J, Tyson D S, Jursikova K, et al. Lumine- scence lifetime based sensor for cyanide and related anions [J]. J Am Chem Soc,2002,124:6232 - 6233.
  • 8Suzuki T, Hiolki A, Kurahashi M. Development of a meth- od for estimating an accurate equivalence point in nickel titration of cyanide ions [J]. Analy Chim Acta, 2003,476 : 159 - 165.
  • 9Safavi A, Maleki N, Shahbaazi H R. Indirect determination of cyanide ion and hydrogen cyanide by adsorptive strip- ping vohammetry at a mercury electrode [J]. Analy Chim Acta,2OIM,503:213 - 221.
  • 10Ishii A,Seno H,Watanabe-Suzuki K,et al. Determination of cyanide in whole blood by capillary gas chromatogra- phy with cryogenic oven trapping[J]. Analy Chem, 1988, 70:4873 - 4876.

二级参考文献13

  • 1Luo J D, Xie Z L, Lam J W Y, et al. Aggregation-induced emission of 1-methyl-l, 2,3,4,5-pentaphenylsilole [ J ]. Chem Commun,2001,18 : 1 740-1 741.
  • 2Chen J W, Xu B, Ying X, et al. Aggregation induced emis- sion of cis, cis-1,2,3,4-tetraphenylbutadiene from restrict- ed intramolecular rotatio [ J ]. J Phys Chem A, 2004, (108) :7 522-7 526.
  • 3Hong Y, Lam J W Y, Tang B Z. Aggregation-induced e- mission: Phenomenon, mechanism and applications [ J]. Chem Commun,2009,29 :4 332-4 353.
  • 4Deans R,Kim J, Machacek M R,et al. A poly(p-pheny- leneethynylene) with a highly emissive aggregated phase [J]. J. Am. Chem. Soc,2000,122:8 565-8 566.
  • 5An B K, Kwon S K, Jung S D, et al. Enhanced emission and its switching in fluorescent organic nanoparticles [ J ]. J. Am. Chem. Soc,2002,124:14 410-14 415.
  • 6Yu G, Yin S W, Liu Y Q, et al. Structures, electronic states, photoluminescence, and carrier transport properties of 1, I -disubstituted 2,3,4,5-tetraphenylsiloles [ J ]. J Am Chem Soc,2005,127:6 335-6 346.
  • 7Bhongale C J, Hsu C S. Emission enhancement by forma- tion of aggregates in hybrid chromophoric surfactant am- phiphile/silica nanocomposites[ J ]. Angew Chem lnt Ed, 2006,45:1 404-1 408.
  • 8Qian Y,Li S Y,Zhang G Q,et al. Aggregation-induced e- mission enhancement of 2-( 2 '-hydroxyphenyl) benzothia- zole-based excited-state intramolecular proton-transfer compounds[J]. J Phys Chem B,2007,111:5 861-5 868.
  • 9Huang C Y, Wan C F, Chir J L, et al. A Schiff-based col- orimetric fluorescent sensor with the potential for detection of fluoride Ions[J]. J Fluoresc,2013 ,23 :1 107-1 111.
  • 10Udhayakumari D, Saravanamoorthy S, Ashok M. Simple imine linked colorimetrie and fluorescent receptor for sensing Zn2ions in aqueous medium based on inhibition of ESIPT mechanism [ J]. Tetrahedron Lett, 2011,52:4 631-4 635.

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化学研究与应用
2016年 第4期

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