摘要
由cis-氢化诺卜醇与亚硫酰氯反应制得cis-氢化诺卜基氯,再分别与二甲胺、二乙胺、二正丙胺、二正丁胺、六氢吡啶、吗啉等仲胺反应,合成了6种cis-氢化诺卜基的叔胺,产品GC纯度达95%以上.通过红外光谱、核磁共振谱和质谱分析表征了它们的结构.
Cis-hydronopyl chloride was synthesized by cis-hydronopol and thionyl chloride. Then six kinds of cishydronopyl tertiary amine compounds were synthesized from the reaction of hydronopyl chloride with dimethylamine,diethylamin,diisopropylamin,dipropylamine,dibutylamine,hexahydropyridine and morpholine respectively. The GC content of the products were over 95% and their structures were characterized and analyzed by IR,NMR and MS methods.
出处
《江西师范大学学报（自然科学版）》
CAS
北大核心
2016年第2期179-182,共4页
Journal of Jiangxi Normal University(Natural Science Edition)
基金
国家自然科学基金(31060101)
江西省教育厅科学技术项目(GJJ150427)
南京市科技计划(201301052)资助项目
关键词
氢化诺卜醇
氢化诺卜基氯
叔胺
合成
结构分析
hydronopol
hydronopyl chloride
tertiary amine
synthesis
sturctural analysis
