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meso-位二取代含四氮唑基团的新型卟啉的合成与表征

Synthesis and Characterization of New Type of Imidazolyl-substituted Porphyrin
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摘要 设计并通过一系列化学反应合成了一种"Trans-A_2B_2"型,meso-位二取代的含四氮唑基团的新型锌卟啉化合物ZnPtz。这是一种具有特殊光谱性质和光电化学性质的卟啉衍生物。我们通过卟啉分子的元素分析,紫外吸收光谱,荧光光谱,红外光谱以及核磁共振,质谱等手段表征了它的结构。研究结果表明,产物的结构正确,目标化合物合成成功。目前我们正将其应用于染料敏化太阳能电池。 The new ＆quot;Trans-A2 B2＆quot;type of zinc porphyrin ZnPtz based on meso-two-substituted with tetrazole group was successfully designed and synthesized through a series of chemical reactions .This porphyrin derivative had special spectral properties and photoelectrochemical properties . It was also characterized by elemental analysis , UV-Vis absorption spectra , fluorescence, FT-IR spectra, 1 H NMR （400 MHz） and mass spectra.Experimental results showed that the structure of the product matched with target product .Currently, it was being applied to dye-sensitized solar cell.
作者 吴方圆 刘家成
机构地区 西北师范大学化学化工学院
出处 《广州化工》 CAS 2016年第9期104-106,共3页 GuangZhou Chemical Industry
关键词 卟啉 四氮唑 合成 表征 porphyrin tetrazole synthesis characterization
分类号 O611.4 [理学—无机化学]
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参考文献12

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广州化工
2016年 第9期

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