2,5-降冰片二烯为配体的铑催化剂的合成研究

Study on Synthesis of Rhodium Catalyst with the Ligand of 2,5-norbornadiene

文章合成了以2,5-降冰片二烯(nbd)为配体的铑催化剂并对其表征。铑与NBD即2,5-降冰片二烯配位生成[Rh(nbd)Cl]2,制备的铑催化剂可以催化取代乙炔手性聚合、环丙烷化、丙烯氢甲酰化、烯炔不对称环化等反应,是一类更优良有效的反应催化剂。

In the paper, the synthesis of 2,5-norbomadiene （nbd） as a ligand of the rhodium catalyst and characterized. Rh and nbd ligand generate [Rh（nbd）C1]2, rhodium catalyst may catalyze the polymerization of chiral substituted acetylene, cyclopropanation, propylene hydroformylation, asymmetric enyne cyclization reactions, it is a kind of better effective catalyst.