多组分体系相图中的杠杆原理形式

The Forms of Lever Rule in the Phase Diagram of Multi-component Systems

讨论了两相和三相多组分体系中杠杆原理的两种形式。对两组分体系,利用三相线上的杠杆原理关系式和凝固点降低公式,解释了熔化物体系冷却过程中的步冷曲线。另外,还讨论了三组分体系相图中,同一直线段上三个物系点之间的类杠杆原理关系式。该关系式可以用于不同浓度溶液的配制和三相体系相图的绘制。

Two forms of the lever rule in the two-phase and three-phase regions of a multi-component system are discussed in this article. As for the two-component system, the cooling curves of solutions are explained with the lever rule in a three-phase line and the freezing point depression equation. A similar form of the lever rule is presented for three points on a line segment in a three-phase diagram region. This equation can be exploited to prepare the solution with desired concentrations of a multi-component system and to draw three-phase diagrams.