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New methacrylic imidazolium poly (ionic liquid) gel with super swelling capacity for oil-in-water emulsions

New methacrylic imidazolium poly (ionic liquid) gel with super swelling capacity for oil-in-water emulsions
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摘要 A new polymeric ionic liquid gel was prepared with 1-[(2-methacryloyloxy)ethyl]-3-methylimidazolium bromide(MEMImBr) via radiation-induced polymerization and cross-linking at room temperature.The resultant PMEMImBr gel exhibits high strength and flexibility as well as special swelling behavior in oil-in-water(O/W)emulsions.The swelling behavior of PMEMImBr gel in emulsions is similar to that in water except that the swelling rate in emulsions is slightly smaller than that in water.The organic solvents with higher polarity in the emulsions contribute to the swelling of PMEMImBr gels,and the O/W proportion of emulsion in the swollen gel equals approximately that of original emulsion when the concentration of organic solvent is lower than 0.2 g/g. A new polymeric ionic liquid gel was prepared with 1-[(2-methacryloyloxy)ethyl]-3-methylimidazolium bromide(MEMImBr) via radiation-induced polymerization and cross-linking at room temperature.The resultant PMEMImBr gel exhibits high strength and flexibility as well as special swelling behavior in oil-in-water(O/W)emulsions.The swelling behavior of PMEMImBr gel in emulsions is similar to that in water except that the swelling rate in emulsions is slightly smaller than that in water.The organic solvents with higher polarity in the emulsions contribute to the swelling of PMEMImBr gels,and the O/W proportion of emulsion in the swollen gel equals approximately that of original emulsion when the concentration of organic solvent is lower than 0.2 g/g.
出处 《Nuclear Science and Techniques》 SCIE CAS CSCD 2016年第3期1-10,共10页 核技术(英文)
基金 supported by the National Natural Science Foundation of China (No. 11375019)
关键词 离子液体 甲基咪唑 乳液 凝胶 水油 溶胀行为 能力 膨胀 Poly(ionic liquid)s PMEMImBr gel Radiation cross-linking Swelling Emulsion
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  • 1R.D. Rogers, Materials science-reflections on ionic liquids.Nature 447, 917–918 (2007). doi:10.1038/447917a.
  • 2D. Mecerreyes, Polymeric ionic liquids: broadening the propertiesand applications of polyelectrolytes. Prog. Polym. Sci. 36,1629–1648 (2011). doi:10.1016/j.progpolymsci.2011.05.007.
  • 3A.F.M. Cla′udio, C.F. Marques, I. Boal-Palheiros et al., Developmentof back-extraction and recyclability routes for ionic-liquid-based aqueous two-phase systems. Green Chem. 16, 259–268(2014). doi:10.1039/C3GC41999A.
  • 4J.Y. Yuan, M. Antonietti, Poly(ionic liquid)s: polymers expandingclassical property profiles. Polymer 52, 1469–1482 (2011).doi:10.1016/j.polymer.2011.01.043.
  • 5J. Le Bideau, L. Viau, A. Vioux, Ionogels, ionic liquid basedhybrid materials. Chem. Soc. Rev. 40, 907–925 (2011). doi:10.1039/C0CS00059K.
  • 6T. Ueki, M. Watanabe, Macromolecules in ionic liquids: progress,challenges, and opportunities. Macromolecules 41,3739–3749 (2008). doi:10.1021/ma800171k.
  • 7X.F. Sui, M.A. Hempenius, G.J. Vancso, Redox-active crosslinkablepoly(ionic liquid)s. J. Am. Chem. Soc. 134, 4023–4025(2012). doi:10.1021/Ja211662k.
  • 8D. Batra, D.N.T. Hay, M.A. Firestone, Formation of a biomimetic,liquid-crystalline hydrogel by self-assembly and polymerizationof an ionic liquid. Chem. Mater. 19, 4423–4431(2007). doi:10.1021/Cm062992z.
  • 9J.C. Leroux, Injectable nanocarriers for biodetoxification. Nat.Nanotechnol. 2, 679–684 (2007). doi:10.1038/nnano.2007.339.
  • 10A.S. Utada, E. Lorenceau, D.R. Link et al., Monodisperse doubleemulsions generated from a microcapillary device. Science 308,537–541 (2005). doi:10.1126/science.1109164.

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