期刊文献+
任意字段
题名或关键词
题名
关键词
文摘
作者
第一作者
机构
刊名
分类号
参考文献
作者简介
基金资助
栏目信息

4,7-取代邻菲啰啉衍生物的合成

Synthesis of 4,7-Substituted Phenanthroline Derivatives
下载PDF
导出
摘要 对标题化合物的合成方法进行了研究,通过邻苯二胺和麦氏酸反应,经过热环化生成二氮杂三元环,再经过卤代、乌尔曼反应合成一系列新型标题化合物。所有产物结构经核磁共振氢谱、碳谱、液质、元素分析及红外进行表征。 The synthesis of 4,7-substituted phenanthroline derivatives was investigated.The products were obtained via Ullmann reaction and halogenation sequentially of intermediate compounds provided by thermocyclisation of o-phenylenediamines with meldrum acid.All products were confirmed by^1 HNMR,^13CNMR,LC-MS,elemental analysis and IR.
作者 王为 王伟 刘清雷
机构地区 上海应用技术学院香料香精技术与工程学院
出处 《化学试剂》 CAS 北大核心 2016年第6期575-578,共4页 Chemical Reagents
关键词 邻菲啰啉衍生物 乌尔曼反应 合成 phenanthroline derivatives Ullmann reaction synthesis
分类号 O626.2 [理学—有机化学]
  • 相关文献

参考文献13

  • 1BENCINI A,BENELLI C A,CANESCHI R L,et al. Crys- tal and molecular structure of and magnetic coupling in two complexes containing gadolinium ( m ) and copper (11) ions[J]. J. Am. Chem. Soc. , 1985, 107(26): 8 128-8 136.
  • 2GADET V, MALLAH T, CASTRO I, et al. Molecular- based magnets: a ferromagnetic bimetallic chromium ( In )-nickel( l] ) cyanide with T =90 K[J]. J. Am. Chem. Soc. ,1992,114(23) :9 213-9 219.
  • 3DUJARDIN E, FERLAY S, PHAN X, et al. Synthesis and magnetization of new room-temperature molecule-based magnets:effect of stoichiometry on local magnetic struc- ture by X-ray magnetic circular dichroism [ J ]. J. Am. Chem. Soc. ,1998,120(44) :11 347-11 351.
  • 4TANASE T, ANDRUH M, MULLER A, et al. Construction of 3d ~ 4f hetero metallic coordination polymers by simul- taneous use of hexacyanometalate building-blocks andexo-bidentate ligands [ J ]. Chem. Commun. , 2001, 12 (12) : 1 084.1 085.
  • 5LONG D L,BLAKE A J,CHAMPNESS N R,et al. Un- precedented seven- and eight-connected lanthanide coor- dination networks [ J ]. Angew. Chem. Int. Ed. Engl. , 2001,113(13) :2 510-2 513.
  • 6EUGENE N, POLLACK N, ANTONIO N, et al. Determi- nation of iron( ]I ) in the presence of thousand-to-one ra- tio of iron ( 111 ) using bathophenanthroline [J]. Anal. Chem. , 1967,39 (2) :272.
  • 7MALIK A K. Direct speetrophotometrie determination of ferbam(iron(HI) dimethyldithiocar bamate) in commer- cial sample and wheat grains using 4,7-diphenyl-1,10- phenanthroline [ J ]. J. Agric. Food Chem. , 2000, 48 (12) :5 808-5 811.
  • 8LAMBERT J L,DAVID J M. Speetrophotometric determi- nation of cyanide ion with tris(1,10-phenanthroline) iron ( ]I ) triiodide ion association reagent [J]. Anal. Chem. , 1968,40(8) :1 354-1 355.
  • 9YOTSUYANAGI T,MASHITA R Y, AOMURA K. Highly selective and sensitive spectropho-tometrie of iron ( II ) and cobalt( l~ ) with 4-(2-pyridylazo) resoreinol (PAR) [J].Anal. Chem. ,1972,44(6) :1 091-1 093.
  • 10JONES D R,JANSHESKL W C,GOLDMAN D S. Spec- trophotometric determination of reduced and total iron in glass with 1,10-phenanthroline[ J]. Anal. Chem. , 1981, 53(6) :923-924.
化学试剂
2016年 第6期

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部