Pickering乳液模板法制备多孔分子印迹聚合物的进展

Development of Porous Imprinted Polymers Synthesized via Pickering Emulsion Template

对近年来Pickering乳液模板法制备多孔分子印迹聚合物的工作进行了总结,阐述了Pickering单乳液、Pickering双乳液以及Pickering高内相乳液法分别制备中空、多孔微球以及泡沫的结构分子印迹聚合物的过程、界面行为调控和对应构效关系;指出了3类方法的优势、适用范围与存在的不足之处,并对微纳米稳定粒子选择、乳液形成方式、应用领域拓展等方面的研究设想进行了展望.

This work reviews the studies about porous imprinted polymers via Pickering emulsion template. The hollow imprinted polymers,porous imprinted polymers and imprinted polymer foams can be prepared by Pickering single emulsion,Pickering double emulsion and Pickering high internal phase emulsion,respectively,and their interface behaviors and structure-activity relationship were described. Meanwhile,the merits,disadvantages and application fields of three emulsion template were commented. Finally,the expectation of this research containing the selection of micro / nano particles,formation ways of stable emulsion was illustrated.