摘要
A new ternary neodymium zirconium sulfide Nd_2ZrS_5 was synthesized by high-temperature solid-state reaction and structurally characterized by single-crystal X-ray diffraction. It crystallizes in the orthorhombic space group Pnma（No. 62） belonging to the Y_2HfS_5 structure-type with a = 11.461（4）, b = 8.009（3）, c = 7.315（3） A, Z = 2 and V = 671.5（4）A3. Its structure features NdS_8 and ZrS_7 polyhedra-constructed a 3-D network. The data of magnetic susceptibility indicate its antiferromagnetic-like behavior without magnetic order down to 2 K.
A new ternary neodymium zirconium sulfide Nd_2ZrS_5 was synthesized by high-temperature solid-state reaction and structurally characterized by single-crystal X-ray diffraction. It crystallizes in the orthorhombic space group Pnma（No. 62） belonging to the Y_2HfS_5 structure-type with a = 11.461（4）, b = 8.009（3）, c = 7.315（3） A, Z = 2 and V = 671.5（4）A3. Its structure features NdS_8 and ZrS_7 polyhedra-constructed a 3-D network. The data of magnetic susceptibility indicate its antiferromagnetic-like behavior without magnetic order down to 2 K.
基金
Supported by Higher Education Science Foundation of Jiangsu Province(No.15KJB150031)
State Key Laboratory of Structural Chemistry Fund(No.20150009)
Yangzhou University for the start-up grant
the Priority Academic Program Development of Jiangsu Higher Education Institutions
