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Red phosphorescent organic light-emitting diodes based on a novel host material with thermally activated delayed fluorescent properties 被引量:2

Red phosphorescent organic light-emitting diodes based on a novel host material with thermally activated delayed fluorescent properties
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摘要 High cost of phosphors and significant efficiency roll-off at high brightness are the two main factors that limit the wide application of phosphorescent organic light-emitting diodes (PHOLEDs). Efforts have been paid to find ways to reduce the phosphors' concentration and efficiency roll-off of PHOLEDs. In this work, we reported red emission PHOLEDs with low dopant concentration and low efficiency roll-off based on a novel host material 2,4-biscyanophenyl-6-(12-phenylindole[2,3-a]carbazole-ll-yl)-1,3,5-triazine (BCPICT), with thermally activated delayed fluorescent (TADF) properties. The device with 1.0% dopant concentration displayed a maximum external quantum efficiency of 10.7%. When the dopant concentration was increased to 2.0%, the device displayed a maximum external quantum efficiency of 10.5% and a low efficiency roll-off of 5.7% at 1000 cd/m^2. High cost of phosphors and significant efficiency roll-off at high brightness are the two main factors that limit the wide application of phosphorescent organic light-emitting diodes (PHOLEDs). Efforts have been paid to find ways to reduce the phosphors’ concentration and efficiency roll-off of PHOLEDs. In this work, we reported red emission PHOLEDs with low dopant concentration and low efficiency roll-off based on a novel host material 2,4-biscyanophenyl-6-(12-phenylindole[2,3-a]carbazole-11-yl)-1,3,5-triazine (BCPICT), with thermally activated delayed fluorescent(TADF) properties. The device with 1.0% dopant concentration displayed a maximum external quantum efficiency of 10.7%.When the dopant concentration was increased to 2.0%, the device displayed a maximum external quantum efficiency of 10.5% and a low efficiency roll-off of 5.7% at 1000 cd/m2.
出处 《Science China Chemistry》 SCIE EI CAS CSCD 2016年第6期684-691,共8页 中国科学(化学英文版)
基金 supported by the National Natural Science Foundation of China (51525304) the National Key Basic Research and Development Program of China (2015CB655002)
关键词 phosphorescent organic light-emitting diodes red emission efficiency roll-off thermally activated delayed fluorescence 基质材料 延迟荧光 有机发光二极管 热激活 荧光性质 磷光 有机电致发光器件 基础
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