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Iron-Mediated Chlorotrifluoromethylation of Alkenes with Sodium Trifluoromethanesulfinate

Iron-Mediated Chlorotrifluoromethylation of Alkenes with Sodium Trifluoromethanesulfinate
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摘要 An iron-mediated three-component chlorotrifluoromethylation of both styrenes and aliphatic alkenes has been presented here. This reaction employs ferric chloride (FeC13) as the CI source and the Langlois reagent (CF3SO2Na) as the CF3 source. It provides a convenient pathway towards a wide range of chlorotrifluoromethylated compounds. An iron-mediated three-component chlorotrifluoromethylation of both styrenes and aliphatic alkenes has been presented here. This reaction employs ferric chloride (FeC13) as the CI source and the Langlois reagent (CF3SO2Na) as the CF3 source. It provides a convenient pathway towards a wide range of chlorotrifluoromethylated compounds.
出处 《Chinese Journal of Chemistry》 SCIE CAS CSCD 2016年第5期465-468,共4页 中国化学(英文版)
关键词 chlorotrifluoromethylation ALKENE Langlois reagent RADICAL chlorotrifluoromethylation, alkene, Langlois reagent, radical
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