期刊文献+

基于聚苯胺-碳纳米管复合物的铅炭电池性能研究 被引量:2

Research on the performance of lead-carbon battery based on polyaniline-carbon nanotubes complex
下载PDF
导出
摘要 本文中,采用化学聚合物制备聚苯胺–碳纳米管复合物,并将其作为负极添加剂,得到了具有优异高倍率部分荷电态循环寿命和充电接受能力的铅炭电池。考察了聚苯胺–碳纳米管复合物添加剂对电池性能的影响,结果表明它提高了铅炭电池的化成效率,降低了负极板不可逆硫酸盐化程度及极化行为。 A polyaniline-carbon nanotubes(PANI-CNTs) complex was synthesized by a chemical polymerization process in this paper. By addition of PANI-CNTs in the negative plate, an improved lead-carbon battery with excellent high-rate partial state-of-charge(HRPSo C) cycling and charge acceptance was achieved. The influences of PANI-CNTs additives on the performance of battery were investigated. The results showed that the PANI-CNTs additives increased the efficiency of formation, reduced the irreversible sulfation of negative plate, and decreased the risk of polarization.
出处 《蓄电池》 2016年第3期106-111,150,共7页 Chinese LABAT Man
关键词 铅炭电池 聚苯胺-碳纳米管复合物 多壁碳纳米管 高倍率部分荷电态 负极添加剂 炭材料 极化 铅酸蓄电池 lead-carbon battery polyaniline-carbon nanotubes(PANI-CNTs) complex multi-walled carbon nanotubes high-rate partial state-of-charge negative additives carbon material polarization lead-acid battery
  • 相关文献

参考文献23

  • 1Pavlov D, Nikolov P. Lead-carbon electrodewith inhibitor of sulfation for lead-acid batteries operating in the HRPSoC duty[J]. Journal of The Electrochemical Society, 2012, 159(8): A1215-A1225.
  • 2Moseley P T. Consequences of including carbon in the negative plates of Valve-regulated Lead- Acid batteries exposed to high-rate partial-state- of-charge operation[J]. Journal of Power Sources, 2009, 191(1): 134-138.
  • 3Fernandez M, Valenciano J, Trinidad F, et al. The use of activated carbon and graphite for the development of lead-acid batteries for hybrid vehicle applications[J]. Journal of Power Sources, 2010, 195(14): 4458-4469.
  • 4Zhao L, Chen B, Wang D. Effects of electrochemically active carbon and indium (III) oxide in negative plates on cycle performance of valve-regulated lead-acid batteries during high- rate partial-state-of-charge operation [J]. Journal of Power Sources, 2013, 231: 34-38.
  • 5Ebner E, Burow D, B6rger A, et al. Carbon blacks for the extension of the cycle life in flooded lead acid batteries for micro-hybrid applications[J]. Journal of Power Sources, 2013, 239: 483-489.
  • 6Boden D P, Loosemore D V, Spence M A, et al. Optimization studies of carbon additives to negative active material for the purpose of extending the life of VRLA batteries in high-rate partial-state-of-charge operation[J]. Journal of Power Sources, 2010, 195(14): 4470-4493.
  • 7Dai L, Chang D W, Baek J-B, et al. Carbon nanomaterials for advanced energy conversion and storage[J]. Small, 2012, 8(8): 1130-1166.
  • 8Liu X-M, Huang Z d, Oh S w, et al. Carbon nanotube (CNT)-based composites as electrode material for rechargeable Li-ion batteries: A review [J]. Composites Science and Technology, 2012, 72(2): 121-144.
  • 9Shapira R, Nessim G D, Zimrin T, et al. Towards promising electrochemical technology for load leveling applications: extending cycle life of leadacid batteries by the use of carbon nano-tubes (CNTs) [J]. Energy & Environmental Science, 2013, 6(2): 587-594.
  • 10Saravanan M, Sennu P, Ganesan M, et al. Multi-walled carbon nanotubes percolation network enhanced the performance of negative electrode for lead-acid battery[J]. Journal of The Electrochemical Society, 2013, 160(1): A70-A76.

二级参考文献13

  • 1于成龙.碳纳米管电化学储锂研究进展[J].陕西科技大学学报(自然科学版),2005,23(2):119-125. 被引量:2
  • 2王杏花,张孝彬,余伟良,谭俊军,高云芳,陶新永.铅酸电池添加多壁碳纳米管的作用(英文)[J].材料科学与工程学报,2007,25(6):932-934. 被引量:3
  • 3D. Pavlo,P. Nikolov. Lead-carbon electrode with inhibitor of sulfation for lead-acid batteries operating in the HRPSoC duty[J].{H}Journal of the Electrochemical Society,2012,(08):A1215-A1225.
  • 4J. Xiang,P. Ding,H. Zhang,X.Wu,J.Chen,Y.Yang. Beneficial effects of activated carbon additives on the performance of negative lead-acid battery electrode for high-rate partial-state-of-charge operation[J].{H}Journal of Power Sources,2013.150-158.
  • 5R. Shapira,G. D. Nessim,T. Zimrin,D.Aurbach. Towards promising electrochemical technology for load leveling applications:extending cycle life of lead acid batteries by the use of carbon nano-tubes(CNTs)[J].Energy&Environmental Science,2013,(02):587-594.
  • 6H. Zhang,G. Cao,Y. Yang. Carbon nanotube arrays and their composites for electrochemical capacitors and lithium-ion batteries[J].Energy&Environmental Science,2009,(09):932-943.
  • 7B. Monahov. The beneficial role of carbon in the negative plate of advanced lead-carbon batteries[J].{H}ECS Transactions,2012,(13):45-69.
  • 8孙成.碳素与铅酸蓄电池[J].蓄电池,1999,36(4):38-42. 被引量:7
  • 9陈代武,李绿冰,林目玉,李杰红,傅春燕.铅酸蓄电池添加剂的研究进展[J].电源技术,2012,36(8):1245-1247. 被引量:11
  • 10李现红,范娜,孔德龙,周庆申.特种炭材料改善铅酸蓄电池负极性能的研究[J].蓄电池,2012,49(4):147-150. 被引量:1

共引文献3

同被引文献22

引证文献2

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部