两亲性共聚物共混PVDF超滤膜的界面性质与抗蛋白质污染的研究

Interfacial Property of Amphiphilic Copolymer Blending PVDF UF Membrane and Protein Anti-fouling

考察了两亲性共聚物聚氧乙烯/聚氧丙烯/聚氧乙烯[PEO-PPO-PEO（F127）]共混聚偏氟乙烯（PVDF）铸膜液，在水相凝胶浴中的相转化动力学过程。结合衰减全反射傅立叶转变红外光谱（ATR-FTIR）、扫描电子显微镜（SEM）、原子力显微镜（AFM）等表征手段，分析了 F127含量在 PVDF 膜表面的 PEO 富集率、膜微观形貌及结构参数的影响规律。以静态吸附量、过滤比通量衰减及膜污染阻力模型，评价了 F127/ PVDF 共混膜对牛血清蛋白（BSA）的抗污染性能。结果表明随着 F127添加量增大，相转化延迟分相行为增强，膜表面及内部孔径和孔隙率升高，表面粗糙度增大，膜面 PEO 富集率的增幅在 F127含量达15％后趋于稳定。 F127含量在15％～25％之间的共混膜有较高的渗透通量和 BSA 截留率，静态吸附量低，比通量衰减速度慢，不可逆污染指数低，堵孔阻力及滤饼层阻力分布系数小，表现了良好的抗污染性能。

The phase transformation kinetic process of amphiphilic copolymer polyoxyethylene/ polyoxypropylene/ polyoxyethylene [PEO-PPO-PEO（F127）] blending polyvinylidene fluoride （ PVDF） casting solution in an aqueous gel bath was investigated. The influences of F127 content on the PEO enrichment rate of PVDF membrane surface, membrane morphology and structural parameters were investigated by a total reflection fourier transform infrared spectroscopy （ ATR-FTIR）, scanning electron microscope （ SEM）, atomic force microscopy （AFM） and other analytical techniques. F127 / PVDF blending membrane fouling behavior of bovine serum albumin （BSA） was evaluated by the static adsorption capacity, normalized filtration decay rate and membrane fouling resistance model. The results showed that the membrane delayed phase separation process increased, the membrane surface, internal pore size and porosity increased and the surface roughness increased with increasing F127 addition, and the increment of PEO enrichment rate on the membrane surface became stable when the F127 content reached 15% . F127 blending membranes with F127 contents ranging from 15% to 25% had a higher flux and BSA rejection, lower static adsorption capacity, slower flux decay rate, lower irreversible fouling index and smaller pore blocking resistance and cake layer resistance distribution coefficient, which showed a good anti-fouling property.