5-[2-(对苯偶氮苯氧基)丁氧基]苯基-10,15,20-三[(对甲氧基苯基)]卟啉及其金属配合物的合成

Synthesis of 5-[2-( Para-phenylazo phenyloxy) butoxy]phenyl-10,15,20-tri[( para-metoxyphenyl) ] porphyrin and Its Metal Complexes

以5-[2-(4-溴丁氧基)苯基]-10,15,20-三(对甲氧基苯基)卟啉和对羟基偶氮苯为原料,经取代反应合成新化合物5-[2-(对苯偶氮苯氧基)丁氧基]苯基-10,15,20-三[(对甲氧基苯基)]卟啉(2),2经配位反应合成了金属铜,锌配合物(2a)和(2b),其结构经UV-Vis,1H NMR,IR和元素分析表征。

5- [ 2- （ 4-Para-phenylazophenyloxy ） butoxy ] phenyl- 10,15,20- tri [ （ para-metoxyphenyl ） J porphyrin were synthesized by substitution reaction of 5-[ （2-bromobutoxy） ] phenyl-10, 15,20-tri [（para-metoxy phenyl） ] porphyrin with para-hydroxyazobenzene. The copper（ Ⅱ） and zinc（ Ⅱ ） ion complexes were synthesized via complexing reaction; The structures were characterized by UV-Vis, 1H NMR, IR and elemental analysis.