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Egyptian heavy vacuum gas oil hydrotreating over Co-Mo/CNT and Co-Mo/γ-Al2O3 catalysts 被引量：2

Egyptian heavy vacuum gas oil hydrotreating over Co-Mo/CNT and Co-Mo/γ-Al_2O_3 catalysts
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摘要 The catalytic activity of CoMoS /CNT towards the Egyptian heavy vacuum gas oil hydrotreating was studied. The delivered CNT was functionalized with 6 mol /L HNO_3. The CNT were loaded with 12% MoO_3( by weight) and 0.7 Co /Mo atomic ratio with impregnation methods. The γ-Al_2O_3 catalyst was also prepared by impregnation method to compare both catalysts activities.The analysis tools such XRD,Raman spectroscopy,TEM,and BET were used to characterize the catalysts. The autoclave reactor was used to operate the hydrotreating experiments. The hydrotreating reactions were tested at various operating conditions of temperature 325-375 ℃,pressure 2-6 MPa,time 2-6 h,and catalyst /oil ratio( by weight) of 1 ∶75,1 ∶33 and 1 ∶10. The results revealed that the CoMoS /CNT was highly efficient for the hydrotreating more than the CoMoS /γ-Al_2O_3. Also, the hydrodesulfurization( HDS) increased with increasing catalyst /oil ratio. Additionally,results showed that the optimum condition was temperature 350℃,pressure 4 MPa,catalyst /oil ratio of 1 ∶75 for 2 h. Furthermore,even at low CoMoS /CNT catalyst /oil ratio of 1 ∶75,an acceptable HDS of 77.1% was achieved. The catalytic activity of CoMoS /CNT towards the Egyptian heavy vacuum gas oil hydrotreating was studied. The delivered CNT was functionalized with 6 mol /L HNO3. The CNT were loaded with 12% MoO3（ by weight） and 0.7 Co /Mo atomic ratio with impregnation methods. The γ-Al2O3 catalyst was also prepared by impregnation method to compare both catalysts activities.The analysis tools such XRD,Raman spectroscopy,TEM,and BET were used to characterize the catalysts. The autoclave reactor was used to operate the hydrotreating experiments. The hydrotreating reactions were tested at various operating conditions of temperature 325-375 ℃,pressure 2-6 MPa,time 2-6 h,and catalyst /oil ratio（ by weight） of 1 ∶75,1 ∶33 and 1 ∶10. The results revealed that the CoMoS /CNT was highly efficient for the hydrotreating more than the CoMoS /γ-Al2O3. Also, the hydrodesulfurization（ HDS） increased with increasing catalyst /oil ratio. Additionally,results showed that the optimum condition was temperature 350℃,pressure 4 MPa,catalyst /oil ratio of 1 ∶75 for 2 h. Furthermore,even at low CoMoS /CNT catalyst /oil ratio of 1 ∶75,an acceptable HDS of 77.1% was achieved.
作者 W.Ahmed Hoda,S.Ahmed H.S.El-Sheshtawy Nadia,A.Mohamed Asmaa,I.Zahran
机构地区 Egyptian Petroleum Research Institute Ain-Shams University for Girls
出处 《燃料化学学报》 EI CAS CSCD 北大核心 2016年第7期853-861,共9页 Journal of Fuel Chemistry and Technology
关键词 HYDROTREATMENT HYDRODESULFURIZATION carbon nanotube heavy vacuum gas oil(HVGO) hydrotreatment hydrodesulfurization carbon nanotube heavy vacuum gas oil（HVGO）
分类号 O643 [理学—物理化学]
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  • 1T O P S E H , C L A U S E N B S. Importance of C o - M o - S type structures in hydrodesulfurization[J] . Catal R e v Sci E n g , 1984, 2 6 ( 3 / 4 ) : 3 9 5 420.
  • 2P R I N S R , D E B E E R V H J, S O M O R J A I G A . Structure a n d function of the catalyst a n d the p r o m o t e r in C o - M o hydrodesulfurization catalysts[J] . Catal R e v Sci E n g , 1 9 8 9 , 3 1 ( 1 / 2 ) : 1 - 4 1 .
  • 3M E D I C I L , P R I N S R. T h e influence of chelating ligands o n the sulfidation of N i a n d M o in N i M o / S i 〇2 hydrotreating catalysts[J] . J Catal,1 9 9 6 , 1 6 3 ( 1 ) : 3 8 - 4 9 .
  • 4S H I M I Z U T , H I R O S H I M A K , H O N M A T , M O C H I Z U K I T , Y A M A D A M . Highly active hydrotreatment catalysts prepared with chelatinga g e n t s [J] . Catal today, 1 9 9 8 , 4 5 ( 1 / 4 ) : 2 7 1 - 2 7 6 .
  • 5V A N L O O I J F, V A N D E R L A A N P, S T O R K W H J, D I C A M I L L O D J, S W A I N J. K e y parameters in d e e p hydrodesulfurization of dieself u e l [J] . A p p l C a t a l A : G e n , 1 9 9 8 , 1 7 0 ( 1 ) : 1 - 1 2 .
  • 6S H I M A D A H , S A T O T , Y O S H I M U R A Y , H I R A I S H I J, N I S H I J I M A A . Support effect o n the catalytic activity a n d properties of sulfidedm o l y b d e n u m catalysts [J] . J Catal, 1 9 8 8 , 1 1 0 ( 2 ) : 2 7 5 - 2 8 4 .
  • 7V I S H W A K A R M A S K . S o n o c h e m i c a l a n d impregnated C o - ^ ^ y - A l 2 O 3 catalysts: Performances a n d kinetic studies o n hydrotreatment of lightgas oil [D]. Saskatoon University of S a s k a t c h e w a n , 2007.
  • 8T O P S 囟E H , C L A U S E N B S. Active sites a n d support effects in hydrodesulfurization catalysts[J] . A p p l Catal, 1 9 8 6 , 2 5 ( 1 / 2 ) : 2 7 3 - 2 9 3 .
  • 9E S W A R A M O O R T H I I, S U N D A R A M U R T H Y V , D A S N , D A L A I A K , A D J A Y E J. Application of multi-walled carbon nanotubes asefficient support to N i M o hydrotreating catalyst[J] . A p p l Catal A : G e n , 2 0 0 8 , 3 3 9 ( 2 ) : 1 8 7 - 1 9 5 .
  • 10S I G U R D S O N S, S U N D A R A M U R T H Y V , D A L A I A K , A D J A Y E J. Effect of anodic alu m i n a pore diameter variation o n template-initiatedsynthesis of carbon n a notube catalyst supports[J] . J M o l Catal A : C h e m , 2 0 0 9 , 3 0 6 : 2 3 - 3 2 .

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燃料化学学报
2016年 第7期

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