期刊文献+

亚胺基咪唑离子液体合成及其铑配合物催化烯烃硅氢加成反应 被引量:1

Effect of Amino Imidazole Ionic Liquid on the Rhodium Catalyzed Hydrosilylation of Alkene
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摘要 设计合成了一系列含亚胺氮配体-铑金属催化剂,并将其应用于硅氢加成反应中.结果表明,[Rh(cod)Cl]_2-1a催化体系具有很高的催化活性与β选择性. As well as transition a series of Rh catalyst containing amino nitrogen ligands was synthesized and applied into hydrosilylation reaction. The results showed that [Rh(cod)Cl]2-1a exhibited excellent catalytic activity and β selectivity.
出处 《杭州师范大学学报(自然科学版)》 CAS 2016年第3期225-229,235,共6页 Journal of Hangzhou Normal University(Natural Science Edition)
基金 国家自然科学青年基金项目(21303034 21203049) 浙江省自然科学基金项目(LY14B030007)
关键词 硅氢加成 含氮配体 铑金属催化剂 hydrosilylation nitrogen-containing ligands Rh catalyst
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  • 1ROSENBERG M L, LANGSETH E, KRIVOKAPIC A, et al. Investigation of ligand steric effects on a highly cis-selective Rh(I) cyclopropanation catalyst~J~. New J Chem,2011,35(10) ~2306 2313.
  • 2SASAMORI T, MATSUMOTO T, TOK1TOH N. Synthesis of rhodium-carbonyl complexes bearing a novel P, N-chelating ligand of Schiff-base type[J]. Polyhedron, 2010,29 (1) : 425-433.
  • 3FR.2YSETH M, NETLAND K A, R2~'MMING C, et al. Synthesis and characterization of novel Pd(11) and Pt(11) complexes with 5-ring chelating iminoylcarbene ligands[J]. J Organomet Chem,2005,690(24/25)~6125 6132.
  • 4GUO X Q, WANG Y N, WANG D, et al. Palladium, iridium and ruthenium complexes with acyclic imino-N-heterocyclic earbenes and their application in aqua-phase Suzuki-Miyaura cross-coupling reaction and transfer hydrogenation [J~. Dalton Trans, 2012,41 (48): 14557-14567.
  • 5LEE M, NIU Z B, SLEBODNICK C, et al. Structure and properties of N,N-alkylene Bis(Nqalkylimidazolium) salts[J~. J Phys Chem B,2010,114(21):7312-7319.
  • 6FR.~SETH M, NETLAND K A, TORNROOSK W, et al. Synthesis and characterization of novel Pd(11) complexes with chelating and non-chelating heteroeyclic iminocarbene ligands[J]. Dalton Trans,2005(9) :1664-1674.
  • 7STEINER G, KRAJETE A, KOPACKA H, et al. E1,2]-Rearrangement of imino-N-heterocyclic carbene~ synthesis and structures of chelating iminoimidazole Pd and Ni eomplexes~J~. Eur J Inorg Chem,2004(14) :2827-2836.

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