摘要
设计合成了一系列含亚胺氮配体-铑金属催化剂,并将其应用于硅氢加成反应中.结果表明,[Rh(cod)Cl]_2-1a催化体系具有很高的催化活性与β选择性.
As well as transition a series of Rh catalyst containing amino nitrogen ligands was synthesized and applied into hydrosilylation reaction. The results showed that [Rh(cod)Cl]2-1a exhibited excellent catalytic activity and β selectivity.
出处
《杭州师范大学学报(自然科学版)》
CAS
2016年第3期225-229,235,共6页
Journal of Hangzhou Normal University(Natural Science Edition)
基金
国家自然科学青年基金项目(21303034
21203049)
浙江省自然科学基金项目(LY14B030007)
关键词
硅氢加成
含氮配体
铑金属催化剂
hydrosilylation
nitrogen-containing ligands
Rh catalyst