两种新型单肟配体的合成及表征

Synthesis and Structural Characterization of Two New Monoxime Ligands

以3-乙氧基水杨醛,5-硝基水杨醛和4-氨基苯乙酮为原料合成了两种单肟配体HL^1(1-(4-{[(E)-3-乙氧基-2-羟苯亚甲基]氨基}苯乙酮)甲氧基肟)和HL^2(1-(4-{[(E)-5-硝基-2-羟苯亚甲基]氨基}苯乙酮)甲氧基肟),并进行了两种新型单肟配体的溶解性、元素组成、紫外光谱和红外光谱的分析表征.

Based on raw materials of 3-ethoxy salicylaldehyde, 5-nitro salicylicaldehyde and 4-aminoacetophenone, two kinds of new monoxime ligands HL1 （l -（4-{ [（E）-3-ethoxy-2-hydroxy benzenemethylene]amino}acetophenone）methoxy oxime and HL2 l -（4-{ [（E）-5-nitr〇-2-hydroxy benzenemethylene] amino} acetophenone） methoxy oxime are prepared. And the characteristics of twokinds of ligands,such as solubility, elemental composition, UV spectrum and IR spectrum are analyzed.