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剥离重组法制备层状纳米复合材料α-ZrP/MB 被引量:2

Preparation ofα-ZrP/MB Layered Nanocomposites with the Exfoliation/Restacking Method
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摘要 首先采用修改过的氟配位法制备α-磷酸锆(简写为α-ZrP)无机层状材料,然后通过剥离重组法,用四丁基氢氧化铵溶液将其剥离成纳米片与亚甲基蓝(MB)溶液进行重组,从而制备α-ZrP/MB层状纳米复合材料.采用XRD,SEM,IR和UV-vis等方法对插层复合材料进行表征,并对MB分子在纳米片层间的排列方式进行推测. A novel layered nanomaterial,Zr(HPO4)2,abbreviated asα-ZrP,was synthesized by a slightly modified HF approach.And then it was delaminated into nanosheets by tetra butyl ammonium hydroxide solution and self-assembled with methylene blue aqueous solution using the exfoliation/restacking method.Finally,the obtained intercalating composite,α-ZrP/MB,was characterized by using XRD,SEM,IR and UV-vis.In addition,the arrangement of methylene blue molecules in the nanosheets was speculated.
出处 《淮海工学院学报(自然科学版)》 CAS 2016年第2期33-36,共4页 Journal of Huaihai Institute of Technology:Natural Sciences Edition
基金 连云港市第五期"521高层次人才培养工程"科研项目(KK15041)
关键词 无机层状材料 剥离重组法 Α-磷酸锆 inorganic layered material exfoliation/restacking method α-ZrP
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