摘要
The 0.8 Me V copper （ Cu） ion beam irradiation-induced effects on structural, morphological and optical properties of tin dioxide nanowires （Sn02 NWs） are investigated. The samples are irradiated at three different doses 5 × 10^12 ions/cm2, 1 ×10^13 ions/cm2 and 5 × 10^13 ions/em2 at room temperature. The XRD analysis shows that the tetragonal phase of Sn02 NWs remains stable after Cu ion irradiation, but with increasing irradiation dose level the crystal size increases due to ion beam induced coalescence of NWs. The FTIR spectra of pristine Sn02 NWs exhibit the chemical composition of SnO2 while the Cn-O bond is also observed in the FTIR spectra after Cu ion beam irradiation. The presence of Cu impurity in SnO2 is further confirmed by calculating the stopping range of Cu ions by using TRM/SRIM code. Optical properties of SnO2 NWs are studied before and after Cu ion irradiation. Band gap analysis reveMs that the band gap of irradiated samples is found to decrease compared with the pristine sample. Therefore, ion beam irradiation is a promising technology for nanoengineering and band gap tailoring.
The 0.8 Me V copper （ Cu） ion beam irradiation-induced effects on structural, morphological and optical properties of tin dioxide nanowires （Sn02 NWs） are investigated. The samples are irradiated at three different doses 5 × 10^12 ions/cm2, 1 ×10^13 ions/cm2 and 5 × 10^13 ions/em2 at room temperature. The XRD analysis shows that the tetragonal phase of Sn02 NWs remains stable after Cu ion irradiation, but with increasing irradiation dose level the crystal size increases due to ion beam induced coalescence of NWs. The FTIR spectra of pristine Sn02 NWs exhibit the chemical composition of SnO2 while the Cn-O bond is also observed in the FTIR spectra after Cu ion beam irradiation. The presence of Cu impurity in SnO2 is further confirmed by calculating the stopping range of Cu ions by using TRM/SRIM code. Optical properties of SnO2 NWs are studied before and after Cu ion irradiation. Band gap analysis reveMs that the band gap of irradiated samples is found to decrease compared with the pristine sample. Therefore, ion beam irradiation is a promising technology for nanoengineering and band gap tailoring.
基金
Supported by the Department of Physics,the University of AJK
High Tech.Centralized Instrumentation Lab,the University of AJK,Pakistan
the Experimental Physics Division,and the National Center for Physics,Islamabad Pakistan
