期刊文献+

微流体技术应用于渗透汽化分离正丁醇-水体系的研究

Research of Application of Microfluidic Technology in the Separation of H_2O/N-Butyl Alcohol by Pervaporation
下载PDF
导出
摘要 将膜分离技术与微流体技术的优势相结合,开发设计了新型膜微反应器,该设备比表面积大且扩散距离短,可以强化渗透汽化过程。以正丁醇-水体系的分离效果为实验模型,分析了膜微反应器的渗透汽化性能。在不同料液温度、料液水含量及料液流速条件下,对膜微反应器中正丁醇-水体系的分离性能进行了系统的研究。当料液温度升高时,渗透通量增大。当进口料液水含量升高时,渗透通量明显增大。当流速升高时,渗透通量增大且趋势逐渐变缓。在实验研究的基础上,建立了渗透汽化传质模型,模型计算值与实验值吻合良好。 A new type of membrane microreactor was designed. The large specific surface area and short diffusion distance of the membrane microreaetor can be used to strengthen the pervaporation process. The system of n-butyl alcohol-water was chosen as the experimental probe to investigate the performance ofpervaporation process in the membrane microreactor. The separating performance of n-butyl alcohol-water system was systematically analyzed under different condition of temperature, content and flow velocity of feed. The permeation flux increased and the water content at the outlet decreased with t he increase of temperature. The permeation flux and the water content at the outlet both increased with the increase of the water concentration at the inlet. As the flow velocity of feed increased, the permeation flux and the water content at the outlet both increased and the trend of increase of permeate flux became slow gradually.
出处 《水处理技术》 CAS CSCD 北大核心 2016年第7期49-53,61,共6页 Technology of Water Treatment
关键词 膜微反应器 渗透汽化 膜分离 过程强化 微尺度 传质模型 membrane microreactor pervaporation membrane separation process intensification
  • 相关文献

参考文献11

  • 1刘琨,童张法.渗透汽化技术在液体分离中的研究新进展[J].现代化工,2005,25(7):18-21. 被引量:8
  • 2骆广生,王凯,吕阳成,徐建鸿,邵华伟.微反应器研究最新进展[J].现代化工,2009,29(5):27-31. 被引量:40
  • 3Kussul E M, Rachkovskij D A, Baidyk T N. Micromechanical engineering: A basis for the low-cost manufacturing of mechanical microdevices using microequipment[J].J Micromech Microeng, 1996,6(4):410-423.
  • 4Scriven L E. Physics and applications of dip coating and spin coating [J]. Materials Research Society,1988,121:717-722.
  • 5Kew P A, Comwell K. Correlations for the prediction of boiling heat transfer in small-diameter channels[J].Applied Thermal Engineering, 1997,17:705-715.
  • 6Kim H J, Nah S S, Min B R. A new technique for preparation of PDMS pervaporation membrane for VOC removal[J].Advances in Environmental Research,2002,6(3):255-264.
  • 7陈镇,刘家祺.水中脱除VOC渗透汽化传质模型的研究[J].高校化学工程学报,2004,18(1):7-12. 被引量:9
  • 8He D, Ma M, Zhao Z. Transport of cadmium ions through a liquid membrane containing amine extractants as carriers[J].J Memb Sci, 2000,169(1):53-59.
  • 9Miyata T, Higuchi J, Okuno H. Preparation of polydimethylsiloxane/ polystyrene interpenetraing polymer network membranes and permeation of aqueous ethanol solutions through the membranes by pervapomtion[J].J Appl Polym Sci, 1996,61:1315-1324.
  • 10Chung J B, Derocher J P, Cussler E L. Distillation with nanoporous or coated hollow fibers[J].J Memb Sci,2005,257(1/2):3-10.

二级参考文献76

  • 1张立平,蒋维钧.渗透汽化法分离丙酮水溶液[J].高校化学工程学报,1994,8(2):187-189. 被引量:10
  • 2Taha T, Cui Z F. CFD modelling of slug flow inside square capillaries [J]. Chemical Engineering Science,2006,61:665 - 675.
  • 3Qu w L, Mudawar I. Flow boiling heat transfer in two-phase microchannel heat sinks: I. Experimental investigation and assessment of correlation methods[J]. International Journal of Heat and Mass Transfer, 2003,46(15) :2755 - 2771.
  • 4Li S W, Xu J H, Wang Y J, et al. Mesomixing scale controlling and its effect on micromixing performance[J].Chemical Engineering Science, 2007,62(13) : 3620 - 3626.
  • 5Xu J H, Tan J, Li S W, et al. Enhancement of mass transfer performance of liquid-liquid system by droplet flow in microchannels [ J ]. Chemical Engineering Journal, 2008,141 (1/2/3) : 242 - 249.
  • 6Zhao Y C, Chen G W, Yuan Q. Liquid-liquid two-phase mass transfer in the T-junction microchannels [J].MChE Journal, 2007, 53 ( 12 ) : 3042 - 3053.
  • 7Wang K, Lu Y C, Shao H W. Heat transfer performance of liquid/liquid micro-dispersed system[Jl. Industrial & Engineering Chemistry Research, 2008,47(23) :9754 - 9758.
  • 8Schneider M A, Stoessel R. Determination of the kinetic parameters of fast exothermal reactions using a novel microreactor-based calorimeter [J]. Chemical Engineering Journal,2005,115(1/2) :73 - 83.
  • 9Xu J H, Li S W, Tan J, et al. Preparation of highly monodisperse droplet in a T-junction microfluidic device [ J ]. AIChE Journal, 2006,52 (9) : 3005 - 3010.
  • 10Xu J H, Li S, Chen G G, et al. Formation of monodisperse microbubbles in a microfluidic device [ J ]. AIChE Journal, 2006, 52 ( 6 ) : 2254 - 2259.

共引文献54

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部