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Pt/Y2O3:Eu3+ composite nanotubes: Enhanced photoluminescence and application in dye-sensitized solar cells 被引量:6

Pt/Y2O3:Eu3+ composite nanotubes: Enhanced photoluminescence and application in dye-sensitized solar cells
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摘要 Y(OH)3:Eu3+ nanotubes were synthesized using a facile hydrothermal method, and then, Pt particles were grown on the surface of the nanotubes using a combination of vacuum extraction and annealing. The resulting Pt/Y2O3:Eu3+ composite nanotubes not only exhibited enhanced red luminescence under 255- or 468-nm excitation but could also be used to improve the efficiency of dye- sensitized solar cells, resulting in an efficiency of 8.33%, which represents a significant enhancement of 11.96% compared with a solar cell without the com- posite nanotubes. Electrochemical impedance spectroscopy results indicated that the interfacial resistance of the TiO2-dyel I3/I- electrolyte interface of the TiO2-Pt/Y203:Eu3~ composite cell was much smaller than that of a pure TiO2 cell. In addition, the TiO2-Pt/Y2O3:Eu3+ composite cell exhibited a shorter electron transport time and longer electron recombination time than the pure TiO2 cell. Y(OH)3:Eu3+ nanotubes were synthesized using a facile hydrothermal method, and then, Pt particles were grown on the surface of the nanotubes using a combination of vacuum extraction and annealing. The resulting Pt/Y2O3:Eu3+ composite nanotubes not only exhibited enhanced red luminescence under 255- or 468-nm excitation but could also be used to improve the efficiency of dye- sensitized solar cells, resulting in an efficiency of 8.33%, which represents a significant enhancement of 11.96% compared with a solar cell without the com- posite nanotubes. Electrochemical impedance spectroscopy results indicated that the interfacial resistance of the TiO2-dyel I3/I- electrolyte interface of the TiO2-Pt/Y203:Eu3~ composite cell was much smaller than that of a pure TiO2 cell. In addition, the TiO2-Pt/Y2O3:Eu3+ composite cell exhibited a shorter electron transport time and longer electron recombination time than the pure TiO2 cell.
出处 《Nano Research》 SCIE EI CAS CSCD 2016年第8期2338-2346,共9页 纳米研究(英文版)
基金 This work was supported by the National Natural Science Foundation of China (No. 21471050) and Heilongjiang Province Natural Science Foundation of Key Projects (No. ZD201301).
关键词 Pt/Y2O3:Eu3+ NANOCRYSTALS LUMINESCENCE dye-sensitized solar cells Pt/Y2O3:Eu3+, nanocrystals, luminescence, dye-sensitized solar cells
分类号 O [理学]
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