摘要
With the aid of a postsynthetic metathesis method, an inert nitrogen-rich porphyrinic metal-organic framework can exhibit a high catalytic activity in one-pot deacetalization-Knoevenagel condensation reaction.
With the aid ofa postsynthetic metathesis method, an inert nitrogen-rich porphyrinic metal-organic framework can exhibit a high catalytic activity in one-pot deacetalization-Knoevenagel condensation reaction.
基金
Financial support of the ligand and MOFs synthesis in part by the Center for Gas Separations Relevant to Clean Energy Technologies
an Energy Frontier Research Center funded by the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences under Award Number DE-SC0001015
part of the U.S. Department of Energy (DOE), ARPA-e (DE-AR0000249)
DOENational Energy Technology Laboratory Award (DE-FE0026472)
the Welch Foundation under award number A-1725
the Welch Endowed Chair to HJZ (A-0030) for support of the structural analyses
The X-ray diffractometers, and crystallographic computing systems in the X-ray Diffraction Laboratory at the Department of Chemistry, Texas A & M University were purchased with funds provided by the National Science Foundation (CHE-9807975, CHE-0079822, CHE-0215838)
The FESEM acquisition was supported by the NSF (DBI-0116835)
the VP for Research Office, and the TX Eng. Exp. Station. D. Liu and C. Zhong thank the supports of Natural Science Foundation of China (21136001, 21276008)
National Key Basic Research Program of China (2013CB733503)
D.L. also thanks the support of China Scholarship Council (201208110375)
Beijing Higher Education Young EliteTeacher Project (YETP0486)
