摘要
金属及其配合物催化的有机反应由于其快速、高效等优点成为近年来有机化学研究的热点,铁配合物由于其催化活性高、选择性好等优点受到化学家们的广泛关注.综述了近年来发展的铁配合物催化的有机反应,如聚合反应、硅/硼氢化反应、环加成反应、氧化与还原反应、交叉偶联反应以及1,4-加成反应等,并对其发展前景进行了展望.
In recent years, metal and their complexes-catalyzed organic reactions have received much attention in organic chemistry due to their rapidity and efficiency. Iron complexes have attracted much attention from chemical society due to the advantages of high catalytic activity and selectivity. The advances of iron complexes-catalyzed organic reactions are reviewed, such as polymerisation reactions, hydrosilylation/hydroboration, cycloaddition, redox reactions, cross-coupling reactions and 1,4-additions, and the prospects of its development are forecasted.
出处
《有机化学》
SCIE
CAS
CSCD
北大核心
2016年第7期1465-1483,共19页
Chinese Journal of Organic Chemistry
基金
国家自然科学基金(Nos.21172001
21372008)
安徽省自然科学基金(No.1308085QB39)
安徽师范大学博士科研启动基金(No.2016XJJ110)资助项目~~
关键词
催化
铁配合物
有机反应
研究进展
catalysis
iron complexe
organic reaction
research progress
